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Cotton-mouton constants and valency optical scheme for salts of pyridine, quinoline, and isoquinoline

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

A tensor additive scheme has been devised for the optical polarizabilities of the cations of pyridine, quinoline, and isoquinoline. The additional excess charge in these species leads to a decrease in the vertical component of the optical polarizability while the mobility of the electron cloud in the plane of the aromatic ring is retained. This effect is greater in the N-methyl derivatives than in the protonated forms.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, USSR Academy of Sciences, USSR

    S. G. Vul'fson, I. A. Kushnikovskii, A. P. Timosheva & A. N. Vereshchagin

Authors
  1. S. G. Vul'fson
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  2. I. A. Kushnikovskii
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  3. A. P. Timosheva
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  4. A. N. Vereshchagin
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 615–619, March, 1991.

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Vul'fson, S.G., Kushnikovskii, I.A., Timosheva, A.P. et al. Cotton-mouton constants and valency optical scheme for salts of pyridine, quinoline, and isoquinoline. Russ Chem Bull 40, 534–537 (1991). https://doi.org/10.1007/BF00957990

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  • DOI: https://doi.org/10.1007/BF00957990

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