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Structural features of light-sensitive crystals of N′-[2-nitrofurfuryl-5-vinyl]benzhydrazide and [N′-furfurylidene)]benzhydrazide

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

An x-ray structural study found that N′-[2-nitrofurfuryl-5-vinyl]benzhydrazide and [N′-(furfurylidene)]benzhydrazide do not form crystal hydrates although they have polar syn-conformations. Molecules in the crystal are joined by linear chains of intermolecular H-bonds C=O...H-N. The light-sensitivity of the crystals increases with decreasing packing density.

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Literature cited

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    S. M. Aldoshin, I. I. Chuev, L. O. Atovmyan, O. A. Kozina & V. S. Nedzvetskii

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  1. S. M. Aldoshin
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  2. I. I. Chuev
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  3. L. O. Atovmyan
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  4. O. A. Kozina
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  5. V. S. Nedzvetskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1556–1562, July, 1990.

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Aldoshin, S.M., Chuev, I.I., Atovmyan, L.O. et al. Structural features of light-sensitive crystals of N′-[2-nitrofurfuryl-5-vinyl]benzhydrazide and [N′-furfurylidene)]benzhydrazide. Russ Chem Bull 39, 1408–1413 (1990). https://doi.org/10.1007/BF00957849

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  • DOI: https://doi.org/10.1007/BF00957849

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