Conclusions
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1.
3-Hydroxyamino- and 1-hydroxy-3-hydroxyamino-2,2,6,6-tetramethyl-4-piperidone oximes have been obtained by reacting chloroketones derived from triacetonamine with hydroxylamine.
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2.
Condensation of the resulting α-hydroxyaminooximes with benzaldehyde and formaldehyde has given the N-piperidyl-α-phenylnitrones and imidazo[5,4-c]pyridines, and with diacetyl, the pyrido[3,4-b]pyrazine 1,4-dioxides.
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Literature cited
L. N. Yakhontov, Usp. Khim.,8, 1304 (1984).
M. Dagonneau, E. S. Kagan, V. I. Mikhailov, et al., Synthesis, 895 (1984).
L. A. Krinitskaya and L. B. Volodarskii, Izv. Akad. Nauk SSSR, Ser. Khim., 443 (1982).
L. A. Krinitskaya and L. B. Volodarskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1619 (1984).
L. B. Volodarsky (Volodarskii) and A. Ya. Tikhonov, Synthesis, 704 (1986).
L. N. Grigor'eva, A. Ya. Tikhonov, S. A. Amitina, et al., Khim. Geterotsikl. Soedin., 331 (1986).
L. A. Krinitskaya and L. B. Volodarskii, Izv. Akad. Nauk SSSR, Ser. Khim., 391 (1983).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 409–412, February, 1988.
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Volodarskii, L.B., Grigor'eva, L.N., Dulepova, N.V. et al. Preparation of α-hydroxyaminooximes of the triacetonamine series and their reactions with carbonyl compounds. Russ Chem Bull 37, 327–330 (1988). https://doi.org/10.1007/BF00957437
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DOI: https://doi.org/10.1007/BF00957437