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Molecular structure of the products of the dichlorocyclopropanation of the stereoisomeric adducts of cis-alloocimene with acrylonitrile

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An x-ray diffraction structural analysis established the structures of four isomers of 2-(2′,2′-dichloro-3′,3'-dimethylcyclopropyl)-3-cyano-5,6-dimethyl-7-,7-dichlorobicyclo [4.1.0]heptane. These isomers differ relative to the orientation of the condensed cyclopropane ring and cyano group and the orientation of the cyclopropyl substituent in the sixmembered ring.

  2. 2.

    The structural data obtained explain the steric control in the dichlorocyclopropanation of the stereoisomeric adducts of cis-alloocimene with acrylonitrile.

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Literature cited

  1. B. A. Arbuzov, V. V. Ratner, O. I. Danilova, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 5, 1087 (1988).

    Google Scholar 

  2. O. N. Kataeva, I. A. Litvinov, V. A. Naumov, et al., Zh. Strukt. Khim.,30, No. 2, 146 (1989).

    Google Scholar 

  3. V. A. Naumov and V. M. Bezzubov, Dokl. Akad. Nauk SSSR,193, 113 (1970).

    Google Scholar 

  4. L. A. M. Turkenburg, W. H. Wolf, F. Bickelhaupt, et al., J. Am. Chem. Soc.,104, No. 12, 3471 (1982).

    Google Scholar 

  5. N. Nakamura, W. B. Schweizer, B. Frei, et al., Helv. Chim. Acta,63, 2230 (1980).

    Google Scholar 

  6. D. J. Brauer, C. Krüger, and P. J. Roberts, J. Chem. Soc., Perkin Trans. 2, 532 (1976).

    Google Scholar 

  7. D. Ebby, J. Lapasset, L. Pizzala, et al., Acta Crystallogr.,36, 184 (1980).

    Google Scholar 

  8. A. Quick and D. Rogers, J. Chem. Soc., Perkin Trans. 2, 460 (1976).

    Google Scholar 

  9. D. Seebach, R. Dammann, H. J. Lindner, et al., Helv. Chim. Acta,62, No. 4, 1143 (1979).

    Google Scholar 

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    O. N. Kataeva, I. A. Litvinov, V. A. Naumov & V. V. Ratner

Authors
  1. O. N. Kataeva
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  2. I. A. Litvinov
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  3. V. A. Naumov
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  4. V. V. Ratner
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1278–1282, June, 1989.

The authors thank Academician B. A. Arbuzov for participating in a discussion of this work.

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Kataeva, O.N., Litvinov, I.A., Naumov, V.A. et al. Molecular structure of the products of the dichlorocyclopropanation of the stereoisomeric adducts of cis-alloocimene with acrylonitrile. Russ Chem Bull 38, 1164–1167 (1989). https://doi.org/10.1007/BF00957146

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  • DOI: https://doi.org/10.1007/BF00957146

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