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Concentration effects in the catalytic action of metalloporphyrins in nonaqueous media

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The dependence of the effective rate constant of oxidation of cholesterol in the presence of manganese porphyrinates and sodium borohydride on the concentration of the complex of manganese and cholesterol was found.

  2. 2.

    The results obtained were explained within the framework of the hypothesis on formation of solvated associates (dimers) of the manganese porphyrinate-cholesterol, manganese porphyrinate, and cholesterol-cholesterol type.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    A. B. Solov'eva, E. A. Lukashova, A. I. Ivanova & S. A. Vol'fson

Authors
  1. A. B. Solov'eva
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  2. E. A. Lukashova
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  3. A. I. Ivanova
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  4. S. A. Vol'fson
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Additional information

Translated form Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1242–1247, June, 1989.

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Solov'eva, A.B., Lukashova, E.A., Ivanova, A.I. et al. Concentration effects in the catalytic action of metalloporphyrins in nonaqueous media. Russ Chem Bull 38, 1129–1133 (1989). https://doi.org/10.1007/BF00957137

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  • DOI: https://doi.org/10.1007/BF00957137

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