Abstract
Catalytic phosphorylation of α-polyfluoroalkylbenzyl alcohols with excess 1,1-dihydropolyfluoroalkyl dichlorophosphates afforded (1,1-dihydropolyfluoroalkyl) (α-polyfluoroalkylbenzyl) chlorophosphates in a high yield. According to NMR (1H,19F,31P) spectral data, these compounds are a mixture of two diastereomers with a ratio close to the statistical.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1853–1860, August, 1989.
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Goryunov, E.I., Petrovskii, P.V., Shcherbina, T.M. et al. Catalytic phosphorylation of polyfluoroalkanols. Russ Chem Bull 38, 1700–1707 (1989). https://doi.org/10.1007/BF00956959
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DOI: https://doi.org/10.1007/BF00956959