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Dehydration of methylbutanols on mordenites

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dehydration of 2-methyl-2-butanol takes place on weak and strong acid sites, while 3-methyl-2-butanol is primarily dehydrated on the strong acid sites of the catalyst.

  2. 2.

    Dehydration of 2-methyl-2-butanol on mordenites takes place only according to the mechanism of Β-elimination, while 3-methyl-2-butanol is dehydrated according to the mechanism of both Β- and γ-elimination, and an increase in the acidity of the catalyst causes γ-elimination.

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Literature cited

  1. A. I. Maksimov, A. M. Gyul'maliev, I. I. Levitskii, and Kh. M. Minachev, Izv, Akad. Nauk SSSR, Ser. Khim., 339 (1980).

  2. A. I. Maksimov, I. I. Levitskii, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim., 2735 (1981).

  3. H. Karge, J. Ladebeck, Z. Sarbak, and K. Hatada, Zeolites,2, 94 (1982).

    Google Scholar 

  4. É. É. Senderov, A. M. Zubkov, B. A. Lipkind, F. B. Dadashev, I. G. Vorob'eva, and A. V. Lebedkova, Dokl. Akad. Nauk SSSR,256, 884 (1981).

    Google Scholar 

  5. I. V. Mishin, G. A. Piloyan, A. L. Klyachko-Gurvich, and A. M. Rubinshtein, Izv. Akad. Nauk SSSR, Ser. Khim., 1346 (1973).

  6. B. I. Shikunov, L. I. Lafer, and V. I. Yakerson, Dokl. Akad. Nauk SSSR,200, 1119 (1971).

    Google Scholar 

  7. I. V. Mishin, V. A. Plakhotnik, G. I. Kapustin, A. L. Klyachko, and A. A. Slinkin, Kinet. Katal.,24, 1448 (1983).

    Google Scholar 

  8. H. Knözinger, H. Bühl, and K. Kochloefl, J. Catal.,24, 57 (1972).

    Google Scholar 

  9. V. I. Yakerson, L. I. Lafer, and A. M. Rubinshtein, Problems of Kinetics and Catalysis [in Russian], Nauka, Moscow (1975), p. 48.

    Google Scholar 

  10. G. I. Kapustin, T. R. Brueva, A. L. Klyachko, A. D. Rukhadze, and A. M. Rubinshtein, Kinet. Katal.,23, 973 (1982).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    Kh. M. Minachev, A. I. Maksimov, I. V. Mishin, É. É. Senderov & I. I. Levitskii

  2. V. I. Vernadskii Institute of Geochemistry and Analytical Chemistry, Academy of Sciences of the USSR, Moscow

    Kh. M. Minachev, A. I. Maksimov, I. V. Mishin, É. É. Senderov & I. I. Levitskii

Authors
  1. Kh. M. Minachev
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  2. A. I. Maksimov
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  3. I. V. Mishin
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  4. É. É. Senderov
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  5. I. I. Levitskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1465–1470, July, 1984.

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Minachev, K.M., Maksimov, A.I., Mishin, I.V. et al. Dehydration of methylbutanols on mordenites. Russ Chem Bull 33, 1346–1351 (1984). https://doi.org/10.1007/BF00956503

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  • DOI: https://doi.org/10.1007/BF00956503

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