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Reaction of o-aminothiophenol with α-acetylenic ketones

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Reaction of 1-phenyl-2-benzoylacetylene and 1-phenyl-2-thenoylacetylene with, o-aminothiophenol in alcohol at 20°C in the presence of triethylamine in glacial acetic acid affords 2,4-diphenyl-6,7-benzo-1-thia-5-azacyclohepta-2,4,6-triene and 1-thenoyl-2-phenyl-2-(2′-aminophenylthio)ethylene respectively.

  2. 2.

    The reaction of terminal α-acetylenic ketones with o-aminothiophenol results in the formation of 3-acylvinyl-2-acylmethylbenzothiazolines.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    A. S. Nakhmanovich, T. E. Glotova, G. G. Skvortsova, T. N. Komarova, V. I. Skorobogatova & Yu. A. Mansurov

Authors
  1. A. S. Nakhmanovich
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  2. T. E. Glotova
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  3. G. G. Skvortsova
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  4. T. N. Komarova
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  5. V. I. Skorobogatova
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  6. Yu. A. Mansurov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1371–1374, June, 1982.

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Nakhmanovich, A.S., Glotova, T.E., Skvortsova, G.G. et al. Reaction of o-aminothiophenol with α-acetylenic ketones. Russ Chem Bull 31, 1221–1224 (1982). https://doi.org/10.1007/BF00955983

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  • DOI: https://doi.org/10.1007/BF00955983

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