Skip to main content
SpringerLink
Log in

10-oxodibenz[b,e]iodinium salts

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The first reported 10-oxodibenz[b,e]iodinium salts were obtained by the oxidative cyclization of o-iodobenzophenone and the oxidation of the methylene unit in the 10H-dibenz-[b,e]iodinium cation. Some of the reactions of these compounds were studied.

  2. 2.

    o-Iodobenzophenone bisbisulfate was isolated and shown not to undergo the Bayer-Williger oxidation but undergoes ready condensation with benzene to form o-benzoyldiphenyliodonium salts and cyclizes upon heating to the 10-oxodibenz[b,e]iodinium cation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. W. H. Saunders, Jr., J. Am. Chem. Soc.,77, 4679 (1955).

    Google Scholar 

  2. Y. Odaira, H. Kubo, and S. Tsutsumi, Technol. Rep. Osaka Univ.,10, No. 363–391, 221 (1960).

    Google Scholar 

  3. A. N. Nesmeyanov, I. N. Lisichkina, A. N. Vanchikov, and T. P. Tolstaya, Dokl. Akad. Nauk SSSR,228, 99 (1976).

    Google Scholar 

  4. F. M. Beringer, L. Kravets, and G. B. Topliss, J. Org. Chem.,30, 1141 (1965).

    Google Scholar 

  5. W. Von E. Doering and L. Speess, J. Am. Chem. Soc.,72, 5515 (1950).

    Google Scholar 

  6. A. I. Gusev and Yu. T. Struchkov, Zh. Strukt. Khim.,12, 1120 (1971).

    Google Scholar 

  7. E. Le Goff, J. Am. Chem. Soc.,84, 3786 (1962).

    Google Scholar 

  8. F. M. Beringer and S. J. Huang, J. Org. Chem.,29, 445 (1964).

    Google Scholar 

  9. W. Wachter, Chem. Ber.,26, 1744 (1893).

    Google Scholar 

  10. C. Raiford, J. Am. Chem. Soc.,47, 1121 (1925).

    Google Scholar 

  11. J. Blackwell and W. J. Hickinbottom, J. Chem. Soc., 1405 (1961).

  12. J. Collete, D. McGreer, R. Crawford, F. Chubb, and R. B. Sandlin, J. Am. Chem. Soc.,78, 3819 (1956).

    Google Scholar 

  13. G. Heyl, J. Prakt. Chem., 59 [2], 434 (1899).

    Google Scholar 

  14. W. Dilthey, F. Quint, and H. Dierichs, J. Prakt. Chem.,151[2], 25 (1938).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    T. P. Tolstaya, L. D. Egorova & I. N. Lisichkina

  2. M. V. Lomonosov Moscow State University, USSR

    T. P. Tolstaya, L. D. Egorova & I. N. Lisichkina

Authors
  1. T. P. Tolstaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. D. Egorova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. N. Lisichkina
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2781–2787, December, 1983.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tolstaya, T.P., Egorova, L.D. & Lisichkina, I.N. 10-oxodibenz[b,e]iodinium salts. Russ Chem Bull 32, 2495–2501 (1983). https://doi.org/10.1007/BF00954481

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00954481

Keywords

Search

Navigation