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Reductive coupling of butyryl chloride in the presence of CoCl(PPh3)3

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Reductive coupling of butyryl chloride with CoCl(PPh3)3 affords 4-heptanone, 4,5-octanedione, 4-hydroxy-5-octanone, 4-butyryloxy-5-octanone, and 4,5-dibutyryloxy-4-octene.

  2. 2.

    A mechanism for the reductive coupling of butyryl chloride is proposed, involving the intermediate formation of an acylcobalt(III) dichloride complex.

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Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    M. G. Vinogradov, A. B. Tuzikov & G. I. Nikishin

Authors
  1. M. G. Vinogradov
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  2. A. B. Tuzikov
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  3. G. I. Nikishin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 847–850, April, 1983.

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Vinogradov, M.G., Tuzikov, A.B. & Nikishin, G.I. Reductive coupling of butyryl chloride in the presence of CoCl(PPh3)3 . Russ Chem Bull 32, 773–775 (1983). https://doi.org/10.1007/BF00953474

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  • DOI: https://doi.org/10.1007/BF00953474

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