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Reaction of boryloxyalkylphosphines with amines

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Electron-acceptor substituents on the carbon atoms attached to the phosphorus atom increase the ability of 1,3,2,5-dioxaboraphosphorinanes to form complexes at the boron atom with tertiary amines.

  2. 2.

    When dissolved in dioxane, the pyridine complexes of stereoisomers of 2,5-diphenyl-4,6-diisopropyl-5-thio-1,3,2,5-dioxaboraphosphorinanes split off pyridine to form stereosiomers of 2,5-diphenyl-4,6-diisopropyl-5-thio-1,3,2,5-dioxaboraphosphorinanes with the retention of the configuration.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, Kazan' Branch, USSR

    B. A. Arbuzov, G. N. Nikonov & O. A. Erastov

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  1. B. A. Arbuzov
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  2. G. N. Nikonov
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  3. O. A. Erastov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 643–648, March, 1986.

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Arbuzov, B.A., Nikonov, G.N. & Erastov, O.A. Reaction of boryloxyalkylphosphines with amines. Russ Chem Bull 35, 588–592 (1986). https://doi.org/10.1007/BF00953232

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  • DOI: https://doi.org/10.1007/BF00953232

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