Conclusions
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1.
The results of calculations on a kinetic scheme in which allowance is made for bifunctional activity of a metal complex are consistent with the experimental data on the kinetics of oxidation of n-decane and isopropylbenzene in systems containing compounds of cobalt and nickel.
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2.
Under variation in the rate of free-radical initiation, passage from catalytic to inhibiting action gives rise to a competition between linear and second-power chain rupture.
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Literature cited
M. A. Kalik, M. L. Kirmalova, M. N. Polonskaya, Ya. L. Gol'dfarb, Izv. Akad. Nauk SSSR, Ser. Khim., 897 (1966).
E. T. Denisov, Rate Constants for Homolytic Liquid-Phase Reactions [in Russian], Nauka, Moscow (1971), pp. 209, 328, 399.
G. M. Bulgakova, A. N. Shchupik, T. P. Skibida, K. I. Zamaraev, and Z. K. Maizus, Dokl. Akad. Nauk SSSR,199, 376 (1971).
A. B. Gagarina and L. A. Smurova, Kinet. Katal.,21, 371 (1980).
R. B. Svitych, A. L. Buchachenko, O. P. Yablonskii, N. N. Rzhevskaya, V. A. Belyaev, and A. A. Petukhov, Kinet. Katal.,17, 73 (1976).
L. A. Smurova, T. V. Sirota, A. B. Gagarina, V. P. Litvinov, é. G. Ostapenko, Ya. L. Gol'dfarb, and N. M. émanuél', Dokl. Akad. Nauk SSSR,198, 1378 (1971).
T. V. Sirota and A. B. Gagarina, Dokl. Akad. Nauk SSSR,245, 1169 (1979).
A. N. Zverev, V. G. Vinogradova, and N. M. émanuél'Izv. Akad. Nauk SSSR, Ser. Khim., 2224 (1975).
M. Ya. Goldenberg and A. V. Krestinin, Preprint, Chernogolovka Inst. Khim. Fiz. Akad. Nauk SSSR, 1974.
O. N. émanuél', A. M. Sakharov, and I. P. Skibida, Izv. Akad. Nauk SSSR, Ser. Khim., 2692 (1975).
L. A. Smurova, V. L. Rubailo, A. B. Gagarina, and N. M. émanuél', Kinet. Katal.,21, 413 (1980).
V. P. Shcheredin and E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim., 1428 (1967).
D. G. Knorre, L. G. Chuchukina, and N. M. émanuél', Zh. Fiz. Khim.,33, 877 (1959).
A. T. Betts and N. Uri, Makromol. Chem.,95, 22 (1966).
L. Pekkarinen, Suonen Kemistilehti,46, 89 (1973).
N. M. émanuél and A. B. Gagarina, Usp. Khim.,35, 619 (1966).
J. F. Black, J. Am. Chem. Soc.,100, 527 (1978).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1987–1993, September, 1982.
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Sirota, T.V., Shvedova, L.A. & Gagarina, A.B. Kinetics of hydrocarbon oxidation in the presence of additives which are active as both catalysts and inhibitors. Russ Chem Bull 31, 1755–1760 (1982). https://doi.org/10.1007/BF00952370
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DOI: https://doi.org/10.1007/BF00952370