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Quantitative description of distribution of isomers formed in reactions of substituted benzenes with electrophilic reagents

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

If we take into account the charge and orbital control at the stage of formation of theπ-complexes and thermodynamic control at the stage of their transformation into theσ-complexes, it is possible to quantitatively describe the distribution of the isomers formed in the reactions of benzene derivatives with electrophilic agents.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1297–1300, June, 1981.

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Koptyug, V.A., Detsina, A.N. & Rogozhnikova, O.Y. Quantitative description of distribution of isomers formed in reactions of substituted benzenes with electrophilic reagents. Russ Chem Bull 30, 1031–1033 (1981). https://doi.org/10.1007/BF00950287

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  • DOI: https://doi.org/10.1007/BF00950287

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