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Complexes of copper(I) halides with bis (trimethylsilyl) acetylene

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The authors have synthesized 1∶1 complexes of bis (trimethylsilyl) acetylene with copper(I) chloride and bromide, and investigated their vibrational spectra.

  2. 2.

    Using x-ray diffraction analysis they have determined the dimer structure of the complex [(Me3SiC≡CSiMe3)·CuCl]2.

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Literature cited

  1. L. P. Yur'eva, Methods of Heteroorganic Chemistry. Type of Organometallic Compounds of Transition Metals [in Russian], Nauka (1975).

  2. L. P. Yur'eva, Methods of Heteroorganic Chemistry. π-Complexes of Transition Metals with Dienes, Arenes, and Compounds with an M-C σ-bond [in Russian], Nauka (1976).

  3. F. L. Carter and E. W. Hughes, Acta Crystallogr.,10, 801 (1957).

    Google Scholar 

  4. S. R. Landor, B. Demetrion, R. Grzeskowiac, and D. F. Pavey, J. Organomet. Chem.,93, 129 (1975).

    Google Scholar 

  5. M. J. Bruce and O. M. Abu Salah, J. Organomet. Chem.,64, C48 (1974).

    Google Scholar 

  6. R. Clark, J. Howard, and P. Woodward, J. Chem. Soc. Dalton Trans., 2027 (1974).

  7. B. F. Coles, P. B. Hitchcock, and D. R. M. Walton, J. Chem. Soc. Dalton Trans., 442 (1975).

  8. H. Buchert and W. Zell, Z. Phys. Chem.,29, 317 (1961).

    Google Scholar 

  9. A. Pignedoli and G. Peyronel, Spectrochim. Acta,32A, 1739 (1976).

    Google Scholar 

  10. A. W. Brodie and C. J. Wilkins, Inorg. Chem. Acta,8, 13 (1974).

    Google Scholar 

  11. D. A. Edwards and R. Ridiards, J. Organomet. Chem.,86, 407 (1975).

    Google Scholar 

  12. T. J. Ledham, D. B. Powell, and J. G. V. Scott, Spectrochim. Acta,29A, 559 (1973).

    Google Scholar 

  13. V. T. Alexanyan, I. A. Garbuzova, I. R. Golding, and A. M. Sladkov, Spectrochim. Acta,31A, 517 (1975).

    Google Scholar 

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2679–2684, December, 1980.

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Aleksandrov, G.G., Gol'ding, I.R., Sterlin, S.R. et al. Complexes of copper(I) halides with bis (trimethylsilyl) acetylene. Russ Chem Bull 29, 1857–1861 (1980). https://doi.org/10.1007/BF00949643

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  • DOI: https://doi.org/10.1007/BF00949643

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