Abstract
Two copper complexes Cu(tta)2(L1)2 (1) and Cu(tta)2(L2)2 (2) are synthesized and characterized by IR spectroscopy, elemental analysis, and single crystal X-ray diffraction. The copper(II) ion of 1 and 2 is in a distorted octahedral environment with four O atoms of the tta ligands and two N atoms of the heterocyclic ligands. The hydrogen bonds play important roles in stabilizing the structures.
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References
L. Qin, J. Hu, M. Zhang, et al., Cryst. Growth Des., 12, 4911–4918 (2012).
B. Ji, D. Deng, L. Ma, et al., CrystEngComm, 15, 4107–4116 (2013).
R. Sen, D. Mal, P. Brandão, et al., CrystEngComm, 15, 2113–2119 (2013).
M. B. Duriska, S. M. Neville, J. Lu, et al., Angew. Chem., Int. Ed., 48, 8919–8922 (2009).
Y.-F. Zeng, X. Hu, F.-C. Liu, et al., Chem. Soc. Rev., 38, 469–480 (2009).
S. K. Langley, B. Moubaraki, and K. S. Murray, Dalton Trans., 39, 5066–5069 (2010).
D. Saha, R. Sen, T. Maity, et al., Dalton Trans., 41, 7399–7408 (2012).
A. Hazra, P. Kanoo, and T. K. Maji, Chem. Commun., 47, 538–540 (2011).
S. Kitagawa and K. Uemura, Chem. Soc. Rev., 34, 109–119 (2005).
J. R. Dimmock, G. A. Zello, E. O. Oloo, et al., J. Med. Chem., 45, 3103–3111 (2002).
S. W. Yee, L. Jarno, M. S. Gomaa, et al., J. Med. Chem., 48, 7123–7131 (2005).
S. Madabhushi, K. K. R. Mallu, V. S. Vangipuram, et al., Bioorg. Med. Chem. Lett., 24, 4822–4825 (2014).
M. Koufaki, T. Fotopoulou, M. Kapetanou, et al., Eur. J. Med. Chem., 83, 508–515 (2014).
S. Emami, A. Foroumadi, M. Falahti, et al., Bioorg. Med. Chem. Lett., 18, 141–146 (2008).
Q. P. Peterson, D. C. Hsu, D. R. Goode, et al., J. Med. Chem., 52, 5721–5731 (2009).
F. Donato, M. G. de Gomes, A. T. R. Goes, et al., Life Sci., 93, 393–400 (2013).
G.-F. Wang, S.-W. Sun, Q.-P. Han, et al., Crystallogr. Rep., 59, 994–999 (2014).
G.-F. Wang, Z. Naturforsch., 70B, 165–169 (2015).
G.-F. Wang, S.-W. Sun, K. Qian, et al., Z. Kristallogr. New Cryst. Struct., 230, 101/102 (2015).
G.-F. Wang, X. Zhang, S.-W. Sun, et al., Crystallogr. Rep., 60, 1032–1037 (2015).
G.-F. Wang, X. Zhang, S.-W. Sun, et al., Crystallogr. Rep., 60, 1038–1043 (2015).
S.-W. Sun, X. Zhang, and G.-F. Wang, Crystallogr. Rep., 60, 1044–1048 (2015).
CrysAlisPro Version 1.171.35.19, P. Agilent Technologies Inc., Santa Clara, CA, USA (2011).
P. T. Beurskens, G. Admiraal, G. Beurskens, et al., The DIRDIF-92Program System, Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands (1992).
G. M. Sheldrick, Program for Crystal Structure Solution, Refinement, University of Göttingen, Germany (2000).
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Original Russian Text © 2018 G.-F. Wang, S.-W. Sun, Y.-C. Wang.
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 1, pp. 164–169, January–February, 2018.
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Wang, GF., Sun, SW. & Wang, YC. Structural Characterization of Two Copper Complexes with 2-Arylidenebenzocycloalkanone Ligands. J Struct Chem 59, 160–165 (2018). https://doi.org/10.1134/S0022476618010249
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DOI: https://doi.org/10.1134/S0022476618010249