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S,S-Complexes of Copper(I) Halides with 1,2-Bis(3,5-dimethyloxazol-4-ylmethylsulfanyl)ethane as New Catalysts for Phenylacetylene Aminomethylation

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Abstract

New metal–heterocycle S,S-complexes based on Cu(I) binary halides and a polydentate ligand, 1,2- bis(3,5-dimethyloxazol-4-ylmethylsulfanyl)ethane have been prepared. The obtained complexes have demonstrated high catalytic activity in aminomethylation of phenylacetylene with N,N,N',N'-tetramethylmethanediamine, bis(oxazolidin-3-yl)methane, or benzaldehyde–piperidine system.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Ufa State Research Center, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Russia

    V. R. Akhmetova, N. S. Akhmadiev, V. M. Yanybin & A. G. Ibragimov

  2. Ufa State Petroleum Technological University, Ufa, Russia

    G. M. Nurtdinova

  3. Bashkir State University, Ufa, Russia

    A. B. Glazyrin

Authors
  1. V. R. Akhmetova
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  2. N. S. Akhmadiev
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  3. G. M. Nurtdinova
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  4. V. M. Yanybin
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  5. A. B. Glazyrin
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  6. A. G. Ibragimov
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Corresponding author

Correspondence to V. R. Akhmetova.

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Original Russian Text © V.R. Akhmetova, N.S. Akhmadiev, G.M. Nurtdinova, V.M. Yanybin, A.B. Glazyrin, A.G. Ibragimov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 7, pp. 1126–1132.

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Akhmetova, V.R., Akhmadiev, N.S., Nurtdinova, G.M. et al. S,S-Complexes of Copper(I) Halides with 1,2-Bis(3,5-dimethyloxazol-4-ylmethylsulfanyl)ethane as New Catalysts for Phenylacetylene Aminomethylation. Russ J Gen Chem 88, 1418–1424 (2018). https://doi.org/10.1134/S1070363218070113

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  • DOI: https://doi.org/10.1134/S1070363218070113

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