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Organoboron compounds. 375. N2-dialkylboryl-N1-alkylbenzamidines

  • V. A. Dorokhov
  • I. P. Yakovlev
  • B. M. Mikhailov
Organic Chemistry

Summary

  1. 1.

    By the action of trialkylboranes on N-alkylbenzamidines, N2-dialkylboryl-N1-alkylbenzamidines (III) have been synthesized.

     
  2. 2.

    The compounds (III) tend to dimerize, this tendency being more pronounced for the compounds with less highly branched alkyl radicals on the B and N atoms.

     
  3. 3.

    By the addition of (III) at a C=N bond of dicyclohexylcarbodiimide, heterocyclic compounds of the chelate type, dialkylboryl[N-(N,N′-dicyclohexylamidino)-N′-alkylbenzamidinates], have been obtained.

     

Keywords

Alkyl Radical Heterocyclic Compound Dicyclohexylcarbodiimide Organoboron Compound Branch Alkyl Radical 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • V. A. Dorokhov
    • 1
  • I. P. Yakovlev
    • 1
  • B. M. Mikhailov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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