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Isomeric transformations of nitrocinnamic ester

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We studied the thermal isomerization ofα-nitrocinnamic ester, and also its isomerization by treatment with certain polar solvents with a basic character. The composition of the obtained equilibrium mixture of geometric isomers is independent of the method of isomerization.

  2. 2.

    The reaction for the nucleophilic addition of methyl alcohol to the Z-isomer ofα-nitrocinnamic ester is accompanied by its isomerization to the E-isomer.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    K. K. Babievskii, V. M. Belikov, I. M. Filatova & N. S. Garbalinskaya

Authors
  1. K. K. Babievskii
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  2. V. M. Belikov
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  3. I. M. Filatova
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  4. N. S. Garbalinskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1608–1611, July, 1973.

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Babievskii, K.K., Belikov, V.M., Filatova, I.M. et al. Isomeric transformations of nitrocinnamic ester. Russ Chem Bull 22, 1556–1558 (1973). https://doi.org/10.1007/BF00930060

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  • DOI: https://doi.org/10.1007/BF00930060

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