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Addition of ω-Carboxyalkyl radicals to olefins, synthesis of DI- and trigarboxylic acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The 1,2,4-butane- and 1,2,5-pentanetricarboxylic acids were obtained via the addition of theβ-carboxyethyl andγ-carboxypropyl radicals to maleic acid.

  2. 2.

    Some g10 and C14 unsaturated dicarboxylic acids were synthesized by the addition ofβ-carboxyethyl radicals to butadiene. The relation between the yield of the products and the ratio of the reactants was determined.

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Literature cited

  1. G. I. Nikishin, E. K. Starostin, and B. A. Golovin, Izv. Akad. Nauk SSSR, Ser. Khim., 825 (1973).

  2. G. I. Nikishin, E. K. Starostin, B. A. Golovin, and E. D. Lubuzh, Izv. Akad. Nauk SSSR, Ser. Khim., 327 (1972).

  3. G. I. Nikishin, E. K. Starostin, and B. A. Golovin, Izv. Akad. Nauk SSSR, Ser. Khim., 2060 (1971).

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  5. V. Karnozhitskii, Organic Peroxides [Russian translation], IL (1961), p. 66.

  6. K. Weigand and G. Hilgetag, Experimental Methods in Organic Chemistry [Russian translation], Khimiya (1968), p. 32.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    E. K. Starostin, B. A. Golovin & G. I. Nikishin

Authors
  1. E. K. Starostin
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  2. B. A. Golovin
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  3. G. I. Nikishin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1557–1560, July, 1974.

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Starostin, E.K., Golovin, B.A. & Nikishin, G.I. Addition of ω-Carboxyalkyl radicals to olefins, synthesis of DI- and trigarboxylic acids. Russ Chem Bull 23, 1476–1478 (1974). https://doi.org/10.1007/BF00929656

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  • DOI: https://doi.org/10.1007/BF00929656

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