Conclusions
-
1.
The reaction of iron dodecacarbonyl with 2, 4, 6-trimethyl-1, 4-cyclohexadiene gives a mixture of isomeric iron tricarbonyl 5-endo-H- and 5-exo-H-1, 3,5-trimethyl-1,3-cyclohexadienes.
-
2.
The treatment of this mixture with trityl fluoborate gave 2,4, 6-trimethylcyclohexadienyliron tricarbonyl tetrafluoborate.
-
3.
The reaction of 1,5,5-trimethyl-3-methylene-1-cyclohexene with iron dodecacarbonyl gives iron tricarbonyl 1,3,5,5-tetramethyl-1, 3-cyclohexadiene, which practically does not react with trityl fluoborate.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
E. O. Fischer and R. D. Fischer, Angew. Chem.,72, 919 (1960).
A. J. Birch, P. E. Cross, J. Lewis, D. A. White, and S. B. Wild, J. Chem. Soc., A 332 (1968); A. J. Birch and M. A. Haas, J. Chem. Soc., 2645 (1971).
R. B. King, T. A. Manuel, and F. G. A. Stone, J. Inorg. Nucl. Chem.,16, 233 (1961).
J. U. Khand, P. L. Pauson, and W. E. Watts, J. Chem. Soc., 2024 (1969).
D. Jones, L. Pratt, and G. Wilkinson, J. Chem. Soc., 4458 (1962).
G. E. Herberich and H. Miller, Chem. Ber.,104, 2781 (1971).
V. A. Koptyug, R. N. Berezina, and V. G. Shubin, Tetrahedron Lett., 675 (1968).
R. Burton, L. Pratt, and G. Wilkinson, J. Chem. Soc., 594 (1961).
O. H. Wheeler, J. Org. Chem.,20, 1672 (1955).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2083–2086, September, 1973.
Rights and permissions
About this article
Cite this article
Piottukh-Peletskii, V.N., Berezina, R.N., Rezbukhin, A.I. et al. Preparation of iron tricarbonyl complexes of methylbenzenonium ions by hydride cleavage reaction. Russ Chem Bull 22, 2027–2030 (1973). https://doi.org/10.1007/BF00929397
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00929397