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Preparation of iron tricarbonyl complexes of methylbenzenonium ions by hydride cleavage reaction

  • V. N. Piottukh-Peletskii
  • R. N. Berezina
  • A. I. Rezbukhin
  • V. G. Shubin
Organic and Biological Chemistry

Conclusions

  1. 1.

    The reaction of iron dodecacarbonyl with 2, 4, 6-trimethyl-1, 4-cyclohexadiene gives a mixture of isomeric iron tricarbonyl 5-endo-H- and 5-exo-H-1, 3,5-trimethyl-1,3-cyclohexadienes.

     
  2. 2.

    The treatment of this mixture with trityl fluoborate gave 2,4, 6-trimethylcyclohexadienyliron tricarbonyl tetrafluoborate.

     
  3. 3.

    The reaction of 1,5,5-trimethyl-3-methylene-1-cyclohexene with iron dodecacarbonyl gives iron tricarbonyl 1,3,5,5-tetramethyl-1, 3-cyclohexadiene, which practically does not react with trityl fluoborate.

     

Keywords

Iron Hydride Cleavage Reaction Tricarbonyl Trityl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • V. N. Piottukh-Peletskii
    • 1
  • R. N. Berezina
    • 1
  • A. I. Rezbukhin
    • 1
  • V. G. Shubin
    • 1
  1. 1.Novosibirsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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