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Reactions of benzoyl and trichloeoacetyl isocyanates with unsaturated ethers and sulfides

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The benzoyl and trichloroacetyl isocyanates react with enol ethers to yield products with a linear structure.

  2. 2.

    Trichloroacetyl isocyanate reacts with vinyl ethyl sulfides to give the 2 + 4-cycloaddition product, and with alkene sulfides of the RSCH=CHR′ type to give produots with a linear structure. Benzoyl isocyanate does not react with alkene sulfides.

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Author information

Authors and Affiliations

  1. V. I. Ul'yanov-Lenin Kazan State University, USSR

    B. A. Arbuzov, N. N. Zobova & F. B. Balabanova

Authors
  1. B. A. Arbuzov
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  2. N. N. Zobova
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  3. F. B. Balabanova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2056–2060, September, 1973.

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Arbuzov, B.A., Zobova, N.N. & Balabanova, F.B. Reactions of benzoyl and trichloeoacetyl isocyanates with unsaturated ethers and sulfides. Russ Chem Bull 22, 2002–2005 (1973). https://doi.org/10.1007/BF00929392

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  • DOI: https://doi.org/10.1007/BF00929392

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