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Derivatives of N-α-nitroalkylhydrazines 5. UV spectra and dissociation constants for certain N-α-polynitroalkylhydrazine derivatives

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Interaction between the atoms and groups in the molecule leads to an anomalous positioning of the absorption maxima in the spectra of the N-α-polynitroalkylhydrazine anions.

  2. 2.

    The acidity of the N-α-polynitroalkylhydrazine derivatives is three orders higher than that of the corresponding gem-dinitroalkanes.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1534–1537, July, 1977.

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Vorob'eva, V.V., Slovetskii, V.I., Novikov, S.S. et al. Derivatives of N-α-nitroalkylhydrazines 5. UV spectra and dissociation constants for certain N-α-polynitroalkylhydrazine derivatives. Russ Chem Bull 26, 1408–1411 (1977). https://doi.org/10.1007/BF00928516

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  • DOI: https://doi.org/10.1007/BF00928516

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