Conclusions
-
1.
The method of kinetic enrichment and crystallization from chiral solvents has been used to produce optically active forms of N-alkoxyisoxazolidines with a single asymmetrical center on the nitrogen atom.
-
2.
X-ray analysis has been used to determine the crystallographic and molecular structures of the racemic tetraamide of 2-methoxyisoxazolidine-3,3,5,5-tetracarboxylic acid.
Similar content being viewed by others
Literature cited
R. G. Kostyanovskii and G. V. Shustov, Dokl. Akad. Nauk SSSR,232, 1081 (1977).
K. Muller and A. E. Eschenmoser, Helv. Chim. Acta,52, 1823 (1969).
R. Gree and R. Carrie, Tetrahedron Lett., 2990 (1972); Tetrahedron,32, 683 (1976); Bull. Soc. Chim. France, 1319 (1975); R. Gree, F. Tonnard, and R. Carrie, Tetrahedron Lett., 453 (1973); Tetrahedron,32, 675 (1976); S. L. Ioffe, M. V. Kashutina, V. M. Shitkin, A. Z. Yankelevich, A. A. Levina, and V. A. Tartakovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1341 (1972); G. V. Lagodzinskaya, Zh. Strukt. Khim.,11, 31 (1970); S. I. Al'ber, G. V. Galodzinskaya, G. B. Manelis, and E. B. Fel'dman, Izv. Akad. Nauk SSSR, Ser. Khim., 1451 (1975).
R. G. Kostyanovskii and V. F. Rudchenko, Izv. Akad. Nauk SSSR, Ser. Khim., 1903 (1976).
A. V. Kamernitzky, I. S. Levina, E. I. Mortikova, V. M. Shitkin, and B. S. El'yanova, Tetrahedron,33, 2135 (1977).
V. A. Tartakovskii, I. A. Savost'yanova, and S. S. Novikov, Zh. Org. Khim.,4, 240 (1968).
V. A. Tartakovskii, S. L. Ioffe, and S. S. Novikov, Zh. Org. Khim.,3, 628 (1967).
R. G. Kostyanovskii, V. F. Rudchenko, and V. I. Markov, Izv. Akad. Nauk SSSR, Ser. Khim., 1685 (1975).
R. G. Kostyanovskii and V. F. Rudchenko, Izv. Akad. Nauk SSSR, Ser. Khim., 716 (1977).
R. G. Kostyanovskii, V. F. Rudchenko, A. V. Prosyanik, M. D. Isobaev, I. I. Chervin, and V. I. Markov, Izv. Akad. Nauk SSSR, Ser. Khim., 628 (1977).
M. Dobler, J. D. Dunitz, and D. M. Hawley, Helv. Chim. Acta,52, 1831 (1969).
Y. Delugeard, J. L. Baudour, and F. C. Messager, Cryst. Struct. Commun.,3, 397 (1974).
P. C. Chieh, E. Subramanian, and F. Trotter, J. Chem. Soc., A, 179, 184 (1970).
D. W. J. Cruickshank, Computing Methods and the Phase Problem in X-ray Crystal Analysis, Glasgow (1961).
Rentgen-70. Automatization of a System of Programs for X-ray Crystal Analysis [in Russian], Chernogolovka (1972); V. I. Andrianov, Z. Sh. Safina, and B. L. Tarnopol'skii, Rentgen-75. Automatization of a System of Programs for Crystal Determination [in Russian], Chernogolovka (1975).
L. I. Bogomolova, I. A. Gorker, S. A. Kochetkova, and G. I. Mikhailov, Methods of Preparing Chemical Reagents and Preparations [in Russian], Khimiya (1969), No. 18, p. 50.
F. Arndt and J. Rose, J. Chem. Soc., 1 (1935).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 850–859, April, 1978.
Rights and permissions
About this article
Cite this article
Rudchenko, V.F., D'yachenko, O.A., Chervin, I.I. et al. Asymmetrical unbridged nitrogen 16. The optically active N-alkoxyisoxazolidines and the structure of the tetraamide of 2-methoxyisoxazolidine-3,3,5,5-tetracarboxylic acid. Russ Chem Bull 27, 733–741 (1978). https://doi.org/10.1007/BF00925295
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00925295