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Kinetics and stoichiometry of the reaction of 2,2,6,6-tetramethylpiperidin-1-oxyl with xenon difluoride

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The interaction of 2,2,6,6-tetramethylpiperidin-1-oxyl with xenon difluoride leads to the formation of oxopiperidinium cations through oxidation of the\(\begin{array}{*{20}c} {\backslash \backslash } \\ {//} \\ \end{array} N\mathop - \limits^ \cdot 0\) group, nitroso compounds, through detachment ofβ-hydrogen atoms from the piperidinoxyl radicals by monofluoroxenon radicals, and products resulting from nitroso-compounds oxidation.

  2. 2.

    The interaction of piperidinoxyl with xenon difluoride follows a second-order rate equation. Kinetic parameters have been estimated for this process, and a mechanism developed for it.

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Literature cited

  1. V. A. Golubev, V. V. Solodova, N. N. Aleinikov, B. L. Korsunskii, É. G. Rozentsev, and F. I. Dubovitskii, Izv. Akad. Nauk SSSR, Ser. Khim., 572 (1978).

  2. A. P. Alekseev, V. A. Ivlev, and G. N. Nechiporenko, Zavod. Lab.,37, 627 (1971).

    Google Scholar 

  3. V. A. Golubev, V. D. Sen', I. V. Kulik, and A. L. Aleksandrov, Izv. Akad. Nauk SSSR, Ser. Khim., 2235 (1975).

  4. V. D. Sen', V. A. Golubev, and T. M. Kosheleva, Izv. Akad. Nauk SSSR, Ser. Khim., 747 (1977).

  5. E. K. Kiseleva, Analysis of Fluorine-Containing Compounds [in Russian], Khimiya (1966), p. 74.

  6. C. N. R. Rao and K. R. Bkhaskar, Chemistry of Nitro and Nitroso Groups [Russian translation], Vol. 1, Mir (1972), p. 106.

  7. E. A. Moelwyn-Hughes, Chemical Statics and Kinetics of Solutions, Academic Press (1972).

  8. L. V. Gurvich, G. V. Karachavtsev, V. N. Kondrat'ev, Yu. A. Lebedev, V. A. Medvedev, V. K. Potapov, and Yu. S. Khodeev, Chemical Bond Rupture Energies. lonlzation Potential and Electron Affinities [in Russian], Nauka (1974), p. 30.

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Authors and Affiliations

  1. Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    V. A. Golubev, N. N. Salmina, B. L. Korsunskii, N. N. Aleinikov & F. I. Dubovitskii

Authors
  1. V. A. Golubev
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  2. N. N. Salmina
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  3. B. L. Korsunskii
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  4. N. N. Aleinikov
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  5. F. I. Dubovitskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 778–782, April, 1978.

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Golubev, V.A., Salmina, N.N., Korsunskii, B.L. et al. Kinetics and stoichiometry of the reaction of 2,2,6,6-tetramethylpiperidin-1-oxyl with xenon difluoride. Russ Chem Bull 27, 670–674 (1978). https://doi.org/10.1007/BF00925281

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  • DOI: https://doi.org/10.1007/BF00925281

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