Conclusions
During irradiation in methanol by light with λ ≥ 300 nm, 7-amyl- and 6-amylbicyclo[3.2.0]hept-6-en-2-ones rearrange into derivatives of bicyclo[2.2.1]heptene with the simultaneous addition of the solvent.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2760–2764, December, 1977.
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Serebryakov, É.P., Kulomzina, S.D. & Kucherov, V.F. An unusual rearrangement and addition of solvent during the photolysis of alkyl-substituted bicyclo[3.2.0 ]hept-6-en-2-ones in methanol. Russ Chem Bull 26, 2551–2555 (1977). https://doi.org/10.1007/BF00924563
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DOI: https://doi.org/10.1007/BF00924563