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Reactions of BCl3 with salts of trinitromethane

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The authors have investigated the reaction of BCl3 with R4N[C(NO2)3] (R is CH3 or C2H5). In CHCl3 or liquid BCl3, one obtains unstable complexes R4N[Cl3B ←:C(NO2)3], which decompose at 20°C with evolution of tetraalkylammonium tetrachloroborates and nitrogen tetroxide.

  2. 2.

    They have obtained indirect proof of the possibility of disproportionation of R4N[Cl3BC(NO2)3] to R4NBCl4 and R4N{B[C(NO2)3]4}. Attempts to synthesize R4N{B[C(NO2)3]4} and R4N{Al[C(NO2)3]4} by replacing Cl by C(NO2)3 in R4NBCl4 and R4NAlCl4 led to formation of unstable products, decomposing spontaneously at −30 and −10°C, respectively.

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Literature cited

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Authors and Affiliations

  1. Institute of New Chemical Problems, Academy of Sciences of the USSR, Chernogolovka

    K. V. Titova, E. I. Kolmakova & V. Ya. Rosolovskii

Authors
  1. K. V. Titova
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  2. E. I. Kolmakova
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  3. V. Ya. Rosolovskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1965–1968, September, 1977.

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Titova, K.V., Kolmakova, E.I. & Rosolovskii, V.Y. Reactions of BCl3 with salts of trinitromethane. Russ Chem Bull 26, 1822–1825 (1977). https://doi.org/10.1007/BF00924367

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  • DOI: https://doi.org/10.1007/BF00924367

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