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Geometrical structures of certain cyclopropyl ethers

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The relation of polar and steric effects determines the position of the two-gauche-conformer equilibrium point in the gem-dichlorocyclopropyl alkyl and gem-dichlorocyclopropyl aryl ethers with radical orientation toward the CCl2 and CH2 groups.

  2. 2.

    The C(cy)-O bond polarity varies, depending on whether the molecule does or does not contain vicinal C-Cl bonds.

  3. 3.

    The phenyl radical of cyclopropyl phenyl ether is rotated by 35° with respect to the C-O-C plane.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    B. A. Arbuzov, A. M. Kamalyutdinova, S. G. Vul'fson, A. N. Vereshchagin, S. M. Shostakovskii, T. K. Voropaeva & A. A. Retinskii

  2. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    B. A. Arbuzov, A. M. Kamalyutdinova, S. G. Vul'fson, A. N. Vereshchagin, S. M. Shostakovskii, T. K. Voropaeva & A. A. Retinskii

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  1. B. A. Arbuzov
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  2. A. M. Kamalyutdinova
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  3. S. G. Vul'fson
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  4. A. N. Vereshchagin
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  5. S. M. Shostakovskii
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  6. T. K. Voropaeva
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  7. A. A. Retinskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 599–604, March, 1978.

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Arbuzov, B.A., Kamalyutdinova, A.M., Vul'fson, S.G. et al. Geometrical structures of certain cyclopropyl ethers. Russ Chem Bull 27, 515–520 (1978). https://doi.org/10.1007/BF00923928

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  • DOI: https://doi.org/10.1007/BF00923928

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