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Synthesis and structure of trimethylsilyl and diethylboron derivatives of p-toluene-N-nitrosulfonamide

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The silylation of the Ag salt of N-nitro-p-toluenesulfonamide with trimethylchlorosilane, or of the free N-nitro-p-toluenesulfonamide with N,N′-diphenyl-N-trimethylurea, gave the O-trimethylsilyl derivative of N-nitro-p-toluenesulfonamide.

  2. 2.

    The reaction of the Ag salt of N-nitro-p-toluenesulfonamide with diethylboron chloride gave the O-diethylboron derivative of N-nitro-p-toluenesulfonamide. Treatment of the derivative with pyridine gave the bis(pyridyldiethylboronium) salt of N-nitro-p-toluenesulfonamide.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    S. L. Ioffe, L. M. Leont'eva, L. M. Makarenkova, A. I. Blyumenfel'd, V. F. Pyaterikov & V. A. Tartakovskii

Authors
  1. S. L. Ioffe
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  2. L. M. Leont'eva
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  3. L. M. Makarenkova
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  4. A. I. Blyumenfel'd
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  5. V. F. Pyaterikov
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  6. V. A. Tartakovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1146–1151, May, 1975.

The authors express their gratitude to O. A. Luk'yanov and N. I. Shlykova for supplying the samples of compounds (IV) and (V), and for the information on the IR spectra of these products.

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Ioffe, S.L., Leont'eva, L.M., Makarenkova, L.M. et al. Synthesis and structure of trimethylsilyl and diethylboron derivatives of p-toluene-N-nitrosulfonamide. Russ Chem Bull 24, 1053–1056 (1975). https://doi.org/10.1007/BF00922963

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  • DOI: https://doi.org/10.1007/BF00922963

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