Skip to main content
Log in

Infrared spectra of catalysts and adsorbed molecules

Communication 19. Investigation of the structure of zeolite

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The IR spectra of a number of modified type Y zeolites, chabazite, erionite, and mordenite were studied in the region of the vibrations of the crystal framework.

  2. 2.

    The region of 550–650 cm−1 is characteristic of all types of zeolites and evidently reflects both the mode of packing of the TO4 tetrahedra and the degree of crystallinity of the zeolite.

  3. 3.

    Cation exchange and decationization in the case of high-silica zeolites have practically no influence on the nature of the spectrum in the region of 550–650 cm−1; the dealuminization of mordenite leads to an increase in the intensity and a shift of them into the high-frequency region.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. S. P. Zhdanov, A. V. Kiselev, V. I. Lygin, and V. I. Titova, Zh. Fiz. Khimii,38, 1299 (1964).

    Google Scholar 

  2. A. C. Wright, J. P. Rupert, and W. T. Granquist, Amer. Mineralogist,53, 1293 (1968).

    Google Scholar 

  3. E. M. Flanigen, H. Khatami, and H. A. Szymanski, The Second International Conference on Molecular Sieve Zeolites, Washington (1970), p. 460.

  4. B. I. Shikunov, L. I. Lafer, V. I. Yakerson, I. V. Mishin, and A. M. Rubenshtein, Izv. Akad. Nauk SSSR, Ser. Khim., 204 (1972).

  5. B. I. Shikunov, L. I. Lafer, V. I. Yakerson, and I. V. Mishin, Izv. Akad, Nauk SSSR, Ser. Khim., 207 (1972).

  6. F. Wolf and H. Furtig, Tonindustrie Zeitung,90, 310 (1966).

    Google Scholar 

  7. F. Wolf, H. Furtig and H. Knoll, Chem. Technik.,23, 368 (1971).

    Google Scholar 

  8. B. I. Shikunov, Dissertation [in Russian], Moscow (1973).

  9. P. Pichat, R. Beaumont, and D. Barthomeuf, Compt. Rend.,C272, 612 (1971).

    Google Scholar 

  10. L. M. Vishnevskaya, A. A. Kubasov, Tkhoang Kho Shi, and K. V. Topchieva, Zh. Fiz. Khimii,47, 1551 (1973).

    Google Scholar 

  11. B. I. Shikunov, L. I. Lafter, V. I. Yakerson, and A. M. Rubinshtein Republican Conference on Molecular Spectroscopy, Summaries of Reports [in Russian], Part 2, “Naukova Dumka,” Kiev (1972), p. 48.

    Google Scholar 

  12. Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, T. A. Isakova, and É. Senderov, Izv. Akad. Nauk SSSR, Ser. Khim., 1738 (1969).

  13. I. V. Mishin, A. L. Klyachko-Gurvich, and A. M. Rubinshtein, Izv. Akad. Nauk SSSR, Ser. Khim., 445 (1973).

  14. A. N. Lazarev, Vibrational Spectra and Structure of Silicates [in Russian], “Nauka” (1968).

  15. I. I. Plyusnina, Infrared Spectra of Silicates [in Russian], Izd-vo Mosk. Un-ta (1967).

  16. L. I. Lafer, E. Z. Golosman, and V. I. Yakerson, Izv, Akad. Nauk SSSR, Ser. Khim., 2696 (1973).

  17. Transactions of the Fourth International Congress on Cement Chemistry [in Russian], Stroiizdat, Moscow (1964).

  18. V. I. Ponomarev, D. M. Kheiker, and N. V. Belov, Dokl. Akad. Nauk SSSR,194, 1072 (1970).

    Google Scholar 

  19. O. Lahordny-Sare and J. L. White, J. Phys. Chem.,75, 2408 (1971).

    Google Scholar 

  20. P. E. Eberly, G. N. Kimberlin, and A. Voorhies, J. Catalysis,22, 419 (1971).

    Google Scholar 

  21. J. Scherzer and J. L. Bass, J. Catalysis,28, 101 (1973).

    Google Scholar 

  22. I. E. Maxwell and A. Baks. Advances Chem. Ser.,121, 87 (1973).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1016–1021, May, 1975.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nabiev, B.A., Lafer, L.I., Yakerson, V.I. et al. Infrared spectra of catalysts and adsorbed molecules. Russ Chem Bull 24, 931–935 (1975). https://doi.org/10.1007/BF00922936

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00922936

Keywords

Navigation