Conclusions
A comparative consideration of the results of the determination of the values of the specific surface of a nickel phase by x-ray diffraction, magnetic, and chemisorption (according to hydrogen and oxygen) methods was conducted for coprecipitated reduced nickel-aluminum oxide catalysts, and analysis was given of the possible causes of discrepancies in the determination of the specific surface of nickel.
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G. D. Lyubarskii, L. B. Avdeeva, and N. V. Kul'kova, Kinetika i Kataliz,3, 123 (1962); G. D. Lyubarskii, V. D. Khor'kov, and V. L. Lopatin, Methods of Investigation of Catalysts and Catalytic Reactions [in Russian], Vol. 2, “Nauka,” Novosibirsk (1965), p. 164.
N. E. Buyanova, A. P. Karnaukhov, L. M. Kefeli, I. T. Ratner, and O. N. Chernyavskaya, Kinetika i Kataliz,8, 868 (1967); N. E. Buyanova, É. V. Kuznetsova, and M. S. Borisova, Zavod. Lab.,35, 154 (1969).
V. I. Yakerson, V. V. Rozanov, Izv. Akad. Nauk SSSR, Ser. Khim., 1461 (1968); V. I. Yakerson, V. V. Rozanov, and A. M. Rubinstein, Surface Sci.,12, 221 (1968).
D. F. Klemperer and F. S. Stone, Proc. Boy., Soc., A243, 375 (1968).
G. Skate and A. Van Rein, Catalysis. Investigation of the Surface of Catalysts [Russian translation], Vol. 10, IL (1960), p. 243.
P. V. Selwood, Adsorption and Collective Paramagnetism, Academic Press, New York (1962), p. 35.
I. V. E. Kunen and B. G. Linsen, in: Structure and Properties of Catalysts and Adsorbents [Russian translation], “Mir” (1973), p. 482.
T. E. Whyte, Catal. Revs.,8, 117 (1973).
M. Prettre, Compt. Rend. Acad. Sic.,C 265, 957 (1967).
M. Pilkuhn and A. Winsel, Z. Electrochem.,63, 1056 (1959).
R. J. Kokes and P. H. Emmert, J. Amer. Chem. Soc.,81, 5032 (1959).
J. Lapujoulade and K. S. Neil, J. Chem. Phys.,57, 3535 (1972); J. Lapujoulade, Supplemento al Nuova Cimento,5, No. 2, 433 (1967).
M. H. Sheridan and K. C. Campbell, J. Catalysis,13, 245 (1969).
P. Feges, F. Nagy, and G. Shey, Acta Chim. Acad. Scient. Hung.,20, 451 (1959).
É. Ya. Ol'shanskii, L. A. Andreev, A. A. Zhukhovitskii, and Ya. V. Ulanovskii, Zh. Fiz. Khimii,41, 2384 (1967).
O. Bik, Catalysis. Problems of Theory of Methods of Investigation [Russian translation], IL (1955), p. 18.
D. V. Sokol'skii and A. M. Sokol'skaya, Metal Catalysts of Hydrogenation [in Russian], “Nauka,” Alma-Ata (1970).
L. Weil, J. Coing-Boyat, M. Prettre, Y. Trambouze, and R. Bassoulas, J. Phys.-Chim. Biol.,62, 552 (1965).
L. Spenadel and M. Boudar, J. Phys. Chem.,64, 204 (1960).
G. A. Mills, S. Weller, and E. B. Cornelius, Actes. 2e Congress International Catalyse, Paris (1960), p. 222.
D. Horiuti and D. Toya, Surface Properties of Solids [Russian translation], “Mir” (1972), p. 11.
V. I. Yakerson and V. V. Rozanov, Results of Science and Technology. Physical Chemistry. Kinetics. Investigation of Catalytic Systems by Methods of Thermodesorption and Thermochromatography [in Russian], VINITI, Moscow (1974), p. 3.
I. I. Zakharov, V. V. Pozumentshchikov, and V. D. Sutula, Kinetikai Kataliz,14, 694 (1973).
G. D. Lyubarskii and N. V. Kul'kova, Dokl. Akad. Nauk SSSR,140, 634 (1961).
Z. Oda, Bull. Chem. Soc. Japan,27, 465 (1954).
N. Scheuble, Z. Physik,135, 125 (1953).
O. Beek, A. E. Smith, and A. Wheeler, Proc. Roy. Soc.,A177, 62 (1940).
M. I. Loktev, Dissertation [inRussian], Moscow (1971).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1003–1008, May, 1975.
The authors would like to express their gratitude to É. A. Fedorovskaya, who performed the magnettic measurements.
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Levina, V.V., Danyushevskii, V.Y., Boevskaya, E.A. et al. Comparative determination of the surface of nickel in Ni-Al2O3 catalysts by various physicochemical methods. Russ Chem Bull 24, 918–922 (1975). https://doi.org/10.1007/BF00922933
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DOI: https://doi.org/10.1007/BF00922933