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Activation of Nickel Oxide Catalysts Modified with Cobalt, Cerium, Manganese, and Zirconium

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Abstract

The activation of a series of catalysts with the general formula Ni0.9M0.1O (M = Co, Ce, Mn, and Zr) synthesized by coprecipitation and the effect of modifying additives on the phase composition and structure of these catalysts were studied. The effect of additives on the initial state of the samples was studied by X-ray diffraction (XRD) analysis, and their role in the process of NiO reduction was studied using in situ XRD analysis and temperature-programmed reduction with hydrogen (TPR-H2). It was found that the modifiers changed the structure and microstructure of the initial samples to increase the specific surface area and decrease the average coherent scattering region (CSR) sizes of NiO. The introduction of Mn and Co led to the formation of substitutional solid solutions with the oxide NiO. For Ce and Zr, the release of the oxide CeO2 and X-ray amorphous ZrOx was observed. The use of these additives led to an increase in the temperature of NiO reduction to a metallic state compared to that of the massive oxide. In addition, the effect of modifying additives on the particle size of the final metal was revealed. The use of Ce and Mn decreased the average CSR size of Ni by a factor of 2–5 compared to that of massive NiO.

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REFERENCES

  1. Alekseeva, M.V., Rekhtina, M.A., Lebedev, M.Y., Zavarukhin, S.G., Kaichev, V.V., Venderbosch, R.H., and Yakovlev, V.A., ChemistrySelect, 2018, vol. 3, p. 5153.

    Article  CAS  Google Scholar 

  2. Kukushkin, R.G., Eletskii, P.M., Bulavchenko, O.A., Saraev, A.A., and Yakovlev, V.A., Catal. Ind., 2019, vol. 11. p. 198.

    Article  Google Scholar 

  3. Smirnov, A.A., Khromova, S.A., Ermakov, D.Y., Bulavchenko, O.A., Saraev, A.A., Aleksandrov, P.V., Kaichev, V.V., and Yakovlev, V.A., Appl. Catal. A: Gen., 2016, vol. 514, p. 224.

    Article  CAS  Google Scholar 

  4. Phimsen, S., Kiatkittipong, W., Yamada, H., Tagawa, T., Kiatkittipong, K., Laosiripojana, N., and Assabumrungrat, S., Energy Convers. Manage., 2017, vol. 151, pp. 324–333.

    Article  CAS  Google Scholar 

  5. Liu, Y., Yao, L., Xin, H., Wang, G., Li, D., and Hu, C., Appl. Catal. B: Environ., 2015, vols. 174–175, p. 504.

    Article  Google Scholar 

  6. Laurent, E. and Delmon, B., Stud. Surf. Sci. Catal., 1994, vol. 88, p. 459.

    Article  CAS  Google Scholar 

  7. Mo, W., Ma, F., Ma, Y., and Fan, X., Int. J. Hydrogen Energy, 2019, vol. 44, p. 24510.

    Article  CAS  Google Scholar 

  8. Sánchez, J., Tallafigo, M.F., Gilarranz, M.A., and Rodríguez, F., Energy Fuels, 2006, vol. 20, p. 245.

    Article  Google Scholar 

  9. Kobayashi, Y., Horiguchi, J., Kobayashi, S., Yamazaki, Y., Omata, K., Nagao, D., Konno, M., and Yamada, M., Appl. Catal. A: Gen., 2011, vol. 395, p. 129.

    Article  CAS  Google Scholar 

  10. Zhang, L., Lin, J., and Chen, Y., J. Chem. Soc., Faraday Trans., 1992, vol. 88, p. 2075.

    Article  CAS  Google Scholar 

  11. Kirumakki, S.R., Shpeizer, B.G., Sagar, G.V., Chary, K.V.R., and Clearfield, A., J. Catal., 2006, vol. 242, p. 319.

    Article  CAS  Google Scholar 

  12. Xu, S., Yan, X., and Wang, X., Fuel, 2006, vol. 85, p. 2243.

    Article  CAS  Google Scholar 

  13. Srinivas, D., Satyanarayana, C.V.V., Potdar, H.S., and Ratnasamy, P., Appl. Catal. A: Gen., 2003, vol. 246, p. 323.

    Article  CAS  Google Scholar 

  14. Fedorov, A.V., Kukushkin, R.G., Yeletsky, P.M., Bulavchenko, O.A., and Yakovlev, V.A., J. Alloys Compd., 2020, vol. 844, p. 156135.

    Article  CAS  Google Scholar 

  15. Ivanova, Y.A., Sutormina, E.F., Isupova, L.A., and Rogov, V.A., Kinet. Catal., 2018, vol. 59, no. 3, p. 537.

    Article  Google Scholar 

  16. Xu, S., Yan, X., and Wang, X., Fuel, 2006, vol. 85, p. 2243.

    Article  CAS  Google Scholar 

  17. Takeguchi, T., Furukawa, S.-N., and Inoue, M., J. Catal., 2001, vol. 202, p. 14.

    Article  CAS  Google Scholar 

  18. Matus, E.V., Shlyakhtina, A.S., Sukhova, O.B., Ismagilov, I.Z., Ushakov, V.A., Yashnik, S.A., Kerzhentsev, M.A., Ismagilov, Z.R., Nikitin, A.P., and Bharali, P., Kinet. Catal., 2019, vol. 60, p. 221.

    Article  CAS  Google Scholar 

  19. Cárdenas-Arenas, A., Bailón-García, E., Lozano-Castelló, D., Da Costa, P., and Bueno-Lopez, A., J. Rare Earths, 2022, vol. 40, no. 1, p. 57.

    Article  Google Scholar 

  20. Aberkane, A., Yeste, M.P., Djazi, F., and Cauqui, M.A., Nanomater, 2022, vol. 12, no. 15, p. 2627.

    Article  Google Scholar 

  21. Parmaliana, A., Arena, F., Frusteri, F., and Giordano, N., J. Chem. Soc., Faraday Trans., 1990, vol. 86, p. 2663.

    Article  CAS  Google Scholar 

  22. Bulavchenko, O.A., Afonasenko, T.N., Sigaeva, S.S., Ivanchikova, A.V., Saraev, A.A., Gerasimov, E.Y., Kaichev, V.V., and Tsybulya, S.V., Top. Catal., 2020, vol. 63, p. 75.

    Article  CAS  Google Scholar 

  23. Arnoldy, P., De Booys, J.L., Scheffer, B., and Moulijn, J.A., J. Catal., 1985, vol. 96, p. 122.

    Article  CAS  Google Scholar 

  24. Garces, L.J., Hincapie, B., Zerger, R., and Suib, S.L., J. Phys. Chem. C, 2015, vol. 119, p. 5484.

    Article  CAS  Google Scholar 

  25. Bulavchenko, O.A., Cherepanova, S.V., Malakhov, V.V., Dovlitova, L.S., Ishchenko, A.V., and Tsybulya, S.V., Kinet. Catal., 2009, vol. 50, p. 192.

    Article  CAS  Google Scholar 

  26. Bulavchenko, O.A., Venediktova, O.S., Afonasenko, T.N., Tsyrul’nikov, P.G., Saraev, A.A., Kaichev, V.V., and Tsybulya, S.V., RSC Adv., 2018, vol. 8, p. 11598.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  27. Stobbe, E.R., de Boer, B.A., and Geus, J.W., Catal. Today, 1999, vol. 47, p. 161.

    Article  CAS  Google Scholar 

  28. Fornasiero, P., Balducci, G., Di Monte, R., Kaspar, J., Sergo, V., Gubitosa, G., Ferrero, A., and Graziani, M., J. Catal., 1996, vol. 164, p. 173.

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The X-ray diffraction studies were performed using the equipment of the Center for Collective Use “National Center for the Study of Catalysts.” The equipment of the Shared Research Center “Siberian Synchrotron and Terahertz Radiation Center” on the basis of the VEPP-4–VEPP-2000 Electron–Positron Collider Complex at the Budker Institute of Nuclear Physics, Siberian Branch, Russian Academy of Sciences was used in this work. The authors are grateful to Z.S. Vinokurov for performing in situ XRD analysis.

Funding

This work was carried out within the framework of a state contract of the Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (project no. AAAA-A21-121011390011-4).

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Authors and Affiliations

  1. Federal Research Center Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    M. D. Mikhnenko, T. N. Afonasenko, V. A. Rogov & O. A. Bulavchenko

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    M. D. Mikhnenko, V. A. Rogov & O. A. Bulavchenko

  3. Center of New Chemical Technologies, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 644040, Omsk, Russia

    T. N. Afonasenko

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  1. M. D. Mikhnenko
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  2. T. N. Afonasenko
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  3. V. A. Rogov
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  4. O. A. Bulavchenko
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Correspondence to M. D. Mikhnenko or O. A. Bulavchenko.

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Translated by V. Makhlyarchuk

Abbreviations and notation: XRD, X-ray diffraction; TPR-H2, temperature-programmed reduction with hydrogen; CSR, coherent scattering region; a, lattice parameter; Ssp, specific surface area.

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Mikhnenko, M.D., Afonasenko, T.N., Rogov, V.A. et al. Activation of Nickel Oxide Catalysts Modified with Cobalt, Cerium, Manganese, and Zirconium. Kinet Catal 64, 484–493 (2023). https://doi.org/10.1134/S0023158423040079

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  • DOI: https://doi.org/10.1134/S0023158423040079

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