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Catalytic Activity of the Oxide Catalysts Based on Ni0.75Co2.25O4 Modified with Cesium Cations in a Reaction of N2O Decomposition

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Abstract

The Ni0.75Co2.25O4 catalysts were prepared by a coprecipitation method and modified with cesium cations by impregnation with a solution of cesium nitrate or cesium nitrate with citric acid and ethylene glycol additives (the Pechini method). The catalysts obtained were investigated by X-ray diffraction analysis, the BET method, X-ray photoelectron spectroscopy, temperature-programmed reduction, and the temperatureprogrammed desorption of oxygen. The activity of the samples in a reaction of nitrous oxide decomposition was determined at temperatures of 200–300°C, in particular, in the presence of oxygen and water in the reaction mixture. It was found that the use of the Pechini method for supporting Cs makes it possible to obtain a more active catalyst, as compared with that prepared by impregnation with cesium nitrate, at the same cesium content (~2%) of the samples.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    Yu. A. Ivanova, E. F. Sutormina, I. A. Isupova & E. I. Vovk

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  1. Yu. A. Ivanova
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  2. E. F. Sutormina
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  3. I. A. Isupova
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  4. E. I. Vovk
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Correspondence to Yu. A. Ivanova.

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Original Russian Text © Yu.A. Ivanova, E.F. Sutormina, I.A. Isupova, E.I. Vovk, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 6, pp. 773–779.

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Ivanova, Y.A., Sutormina, E.F., Isupova, I.A. et al. Catalytic Activity of the Oxide Catalysts Based on Ni0.75Co2.25O4 Modified with Cesium Cations in a Reaction of N2O Decomposition. Kinet Catal 58, 793–799 (2017). https://doi.org/10.1134/S002315841705007X

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  • DOI: https://doi.org/10.1134/S002315841705007X

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