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Reactions of keto alcohols with organophosphorus compounds

Communication 2. Reaction of diacetone alcohol with alkyl dichlorophosphites

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    2-Alkoxy-2-oxo-3, 5, 5-trimethyl-1, 2-oxaphospholan-3-ols were obtained by the reaction of diacetone alcohol with alkyl dichlorophosphites in the presence of a base.

  2. 2.

    A scheme for their formation was proposed.

  3. 3.

    The structure of the 2-alkoxy-2-oxo-3, 5,5-trimethyl-1, 2-oxaphospholan-3-ols is confirmed by the spectroscopy data.

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Literature cited

  1. N. I. Rizopolozhenskii and F. S. Mukhametov, Izv. Akad. Nauk SSSR, Ser. Khim.,1968, 2755.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    N. I. Rizpolozhenskii, F. S. Mukhametov & R. R. Shagidullin

Authors
  1. N. I. Rizpolozhenskii
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  2. F. S. Mukhametov
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  3. R. R. Shagidullin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1121–1125, May, 1969.

The authors express their gratitude to R. B. Nigmatullina for taking the IR spectra.

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Rizpolozhenskii, N.I., Mukhametov, F.S. & Shagidullin, R.R. Reactions of keto alcohols with organophosphorus compounds. Russ Chem Bull 18, 1024–1027 (1969). https://doi.org/10.1007/BF00922863

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  • DOI: https://doi.org/10.1007/BF00922863

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