Conclusions
-
1.
2-Alkyl(aryl)-2-thiono-1,2-oxa-4-phospholenes react with alcohols and mercaptans without ring opening, forming products of addition at the double bond.
-
2.
2-Alkyl(aryl)-2-thiono-1,2-oxa-4-phospholenes react with chloral with formation of 2-alkyl(aryl)-2-oxo-1,2-oxa-4-phospholenes.
Similar content being viewed by others
Literature cited
B. A. Arbuzov, A. O. Vizel', K. M. Ivanovskaya, I. A. Studentsova, and R. S. Ganaev, Dokl. Akad. Nauk SSSR,182, 101 (1968).
A. N. Pudovik, V. K. Khairullin, and R. M. Kondrat'eva, Izv. Akad. Nauk SSSR, Ser. Khim., 2548 (1970).
B. A. Arbuzov and A. O. Vizel', in: Problems of Organic and Physical Chemistry [in Russian], IOFKh im. A. E. Arbuzova AN SSSR, Kazan (1971), p. 84.
N. I. Rizpolozhenskii, V. D. Akamskin, R. M. Eliseenkova, and R. R. Shagidullin, Izv. Akad. Nauk SSSR, Ser. Khim., 2765 (1972).
J. Houben-Weyl, Methoden der Organischene Chemie, Vol. 12/I, Stuttgart (1963), pp. 226, 268, 557.
B. A. Arbuzov, N. I. Rizpolozhenskii, A. O. Vizel', K. M. Ivanovskaya, F. S. Mukhametov, and É. I. Gol'dfarb, Izv. Akad. Nauk SSSR, Ser. Khim., 117 (1971).
H. Sohr and K. Lohs, Z. Chem.,4, 153 (1967).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1589–1592, July, 1976.
Rights and permissions
About this article
Cite this article
Rizpolozhenskii, N.I., Eliseenkova, R.M. & Akamsin, V.D. Certain transformations of 2-alkyl(aryl)-2-thiono-1,2-oxa -4-phospholene derivatives. Russ Chem Bull 25, 1508–1511 (1976). https://doi.org/10.1007/BF00920827
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00920827