Conclusions
On the basis of the measurements of dipole moments and Kerr constants it can be said that the oxides of the thiophene chalcone analogues exist in s-cis and s-trans conformations, these differing in the mutual orientation of oxirane ring and carbonyl group.
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Literature cited
J. L. Pierre, Ann. Chim., 388 (1966).
B. A. Arbuzov, A. I. Donskova, S. G. Vul'fson, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 1498 (1975).
A. N. Vereshchagin, S. G. Vul'fson, A. I. Donskova, and V. I. Savin, Dokl. Akad. Nauk SSSR,215, 339 (1974).
S. G. Vul'fson, A. I. Donskova, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 72 (1975).
V. N. Sheinker, A. S. Kuzharov, A. N. Nazarov, and O. A. Osipov, Zh. Organ. Khim.,11, 1520 (1975).
L. Kaper and T. J. de Boer, Rev. Trav. Chim.,89, 825 (1970).
C. Andrieu and Y. Moller, Bull. Soc. Chim. France, 831 (1969).
H. J. Streurman and H. Schenk, Rec. Trav. Chim.,89, 392 (1970).
R. J. W. Le Fevre, Adv. Phys. Organ. Chem.,3, 1 (1965).
C. L. Cheng, G. J. Ritchie, G. L. D. Ritchie, P. H. Gore, and L. Farnell, J. Chem. Soc. Perkin Trans., 2, 744 (1975).
M. J. Aroney, K. E. Kalderbank, and H. J. Stootman, J. Chem. Soc. Perkin Trans., 2, 1365 (1973).
A. N. Vereshchagin and S. G. Vul'fson, Teor. Éksp. Khim.,4, 548 (1968).
J. L. Pierre and P. Arnaud, Bull. Soc. China. France, 1690 (1966).
B. A. Arbuzov, S. G. Vul'fson, G. G. Butenko, O. A. Samarina, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 94 (1976).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1514–1518, July, 1976.
The authors wish to thank V. I. Savin for having supplied the thienyl cyclopropyl ketone(IX).
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Arbuzov, B.A., Vul'fson, S.F., Donskova, A.I. et al. Spatial structures of substituted oxiranes. Russ Chem Bull 25, 1443–1447 (1976). https://doi.org/10.1007/BF00920815
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DOI: https://doi.org/10.1007/BF00920815