Conclusions
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1.
When the cyclohexane ring is trans-condensed with a five-membered anhydride ring and a bicyclic system the C-C bonds of the bicyclic system occupy equatorial positions.
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2.
The stereochemistry of the diene synthesis of hexachlorocyclopentadiene with the anhydrides of cis- and trans-3-methyl-4-cyclohexene-1,2-dicarboxylic acids is determined by the configuration of the methyl group.
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3.
The addition of maleic anhydride to the diene system of the anhydride of 1,2,3,4-tetracehlorobicyclo[4.4.0]decadiene-8,9-dicarboxylic acid goes in the trans-position to the bonds of the cyclohexane ring.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 869–874, April, 1975.
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Salakhov, M.S., Timosheva, A.P., Vul'fson, S.G. et al. Conformation of cyclohexane ring in some polycyclic molecules. Russ Chem Bull 24, 785–790 (1975). https://doi.org/10.1007/BF00920694
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DOI: https://doi.org/10.1007/BF00920694