Conclusions
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1.
A series of N-(2-hydroxyethyl) alkylidenamines (HEA) was produced by the condensation of ethanolamine with ketones.
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2.
The frequency of the C=N valence vibration in the IR spectra of HEA depends little on the electronic structure of C, N-substituents.
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3.
According to the data of the PMR spectra, HEA exists in two configurations (syn- and anti-isomers).
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4.
The polarographic reduction of HEA was studied; a dependence of the half-wave potential on the existence of an intramolecular hydrogen bond is observed.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 787–793, April, 1975.
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Dmitrieva, Z.T., Skorokhodova, T.S., Polyakova, L.G. et al. Spectral and polarographic characteristics of certain N-(2-hydroxyethyl) alkylidenamines. Russ Chem Bull 24, 709–714 (1975). https://doi.org/10.1007/BF00920679
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DOI: https://doi.org/10.1007/BF00920679