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Spectral and polarographic characteristics of certain N-(2-hydroxyethyl) alkylidenamines

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A series of N-(2-hydroxyethyl) alkylidenamines (HEA) was produced by the condensation of ethanolamine with ketones.

  2. 2.

    The frequency of the C=N valence vibration in the IR spectra of HEA depends little on the electronic structure of C, N-substituents.

  3. 3.

    According to the data of the PMR spectra, HEA exists in two configurations (syn- and anti-isomers).

  4. 4.

    The polarographic reduction of HEA was studied; a dependence of the half-wave potential on the existence of an intramolecular hydrogen bond is observed.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry, Siberian Branch, Academy of Sciences of the USSR, Tomsk

    Z. T. Dmitrieva, T. S. Skorokhodova, L. G. Polyakova, T. M. Velikova & I. F. Bel'skii

Authors
  1. Z. T. Dmitrieva
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  2. T. S. Skorokhodova
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  3. L. G. Polyakova
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  4. T. M. Velikova
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  5. I. F. Bel'skii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 787–793, April, 1975.

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Dmitrieva, Z.T., Skorokhodova, T.S., Polyakova, L.G. et al. Spectral and polarographic characteristics of certain N-(2-hydroxyethyl) alkylidenamines. Russ Chem Bull 24, 709–714 (1975). https://doi.org/10.1007/BF00920679

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  • DOI: https://doi.org/10.1007/BF00920679

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