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Organoboron compounds

Communication 195. Some reactions of B-alkylmercaptoborazoles

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The stepwise partial alkylation of B-tri-n-butylmercaptoborazole with methylmagnesium bromide gave: B-meshyl-B-di-n-butylmercaptoborazole and B-dimethyl-B-n-butylmercaptoborazole.

  2. 2.

    The reaction of B-dimethyl-B-n-butylmercaptoborazole with ethylenediamine gave N,N'-di-(4,6-dimethylborazol-2-yl)-ethylenediamine.

  3. 3.

    The reaction of B-tri-n-butylmercaptoborazole with tetra-n-propyldiborane, taken in a. 2∶1 ratio, gave poly-B-n-butylmercaptoborazole.

  4. 4.

    B-Methyl-B-dichloro-N-trimethylborazole was synthesized by the chlorination of B-methyl-B-di-n-butylmercapto-N-trimethylborazole with mercuric chloride, the trans-halogenation of which gave B-methyl-B-difluoro-N-trimethylborazole.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    B. M. Mikhailov & A. F. Galkin

Authors
  1. B. M. Mikhailov
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  2. A. F. Galkin
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Translated from Izvestiya Akademii Na.uk SSSR, Seriya Khimicheskaya, No. 3, pp. 604–607, March, 1969.

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Mikhailov, B.M., Galkin, A.F. Organoboron compounds. Russ Chem Bull 18, 539–541 (1969). https://doi.org/10.1007/BF00906973

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  • DOI: https://doi.org/10.1007/BF00906973

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