Conclusions
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1.
In the conversion of isopropanol, there is a change in the selectivity of the action of all three oxides (TiO2, ZrO2, HfO2). This is especially sharply manifested on titanium dioxide.
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2.
Titanium, zirconium, and hafnium dioxides are close in physicochemical and catalytic properties.
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3.
A relationship is observed between the specific catalytic activity of the oxides and the structure of the d-shells of their cations.
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Literature cited
T. T. Bakumenko, Catalytic Properties of Rare and Rare Earth Elements [in Russian], Izd. AN USSR, Kiev (1963).
F. Bischoff and H. Adkins, J. Amer. Chem. Soc.,47, 807 (1925).
A. M. Rubinshtein and S. G. Kulikov, Izv. AN SSSR, Otd. Khim. N.,1950, 84.
I. S. Sazonova, T. P. Khokhlova, T. M. Sushentseva, and N. P. Keier, Kinetika i Kataliz,3, 751 (1962).
S. V. Anisimov and G. I. Khaidarov, Zh. Obshch. Khimii,18, 40 (1948).
A. A. Balandin, A. A. Tolstopyatova, and V. A. Ferapontov, Dokl. AN SSSR,103, 611 (1955).
V. I. Yakerson, Dissertation [in Russian], Moscow (1962).
A. Mailhe, J. Usines gaz.,48, 17 (1924); Chem. Abstrs.,18, 1419 (1924).
A. A. Balandin, I. R. Konenko, and A. A. Tolstopyatova, Izv. AN SSSR, Otd. Khim. N.,1961, 47.
K. Bunte, H. Brückner, and G. Choulat, Brennstoff-Chemie,22, 205 (1941).
H. Fehrer and H. Taylor, J. Amer. Chem. Soc.,63, 1385 (1941).
U.S. Patent 2924561 (1960); Chem. Abstrs.,54, 11571 (1960).
B. F. Ormont, Structures of Inorganic Substances [in Russian], Gostekhteoretizdat, Moscow-Leningrad (1950), p. 465.
G. Z. Humphrey, J. Amer. Chem. Soc.,75, 2806 (1953).
L. Breser, U.S. At. Energy Comm. UCRL, 5 (1959).
I. W. Mellor, A. Comprehensive Treatise on Inorganic and Theoretical Chemistry, New York,7, 128 (1931).
A. A. Balandin, A. A. Tolstopyatova, and I. R. Konenko, Izv. AN SSSR, Otd. Khim. N.,1960, 2096.
I. R. Konenko, A. A. Tolstopyatova, and A. A. Balandin, Izv. AN SSSR, Ser. Khim.,1963, 1899.
G. V. Samsonov, Dokl. AN SSSR,93, 689 (1953).
O. V. Krylov, Dissertation [in Russian], Moscow (1964).
G. K. Boreskov, Problems of Physical Chemistry [in Russian], Goskhimizdat, Moscow (1958), No. 1, p. 101.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 496–502, March, 1967.
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Konenko, I.P., Tolstopyatova, A.A. & Balandin, A.A. Catalytic properties of titanium, zirconium, and hafnium dioxides in reactions of dehydrogenation and dehydration. Russ Chem Bull 16, 481–486 (1967). https://doi.org/10.1007/BF00905976
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DOI: https://doi.org/10.1007/BF00905976