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Fe- and Cu–Zn-Containing Catalysts Based on Natural Aluminosilicate Nanotubes and Zeolite H-ZSM-5 in the Hydrogenation of Carbon Dioxide

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

Iron- and Cu–Zn-containing carbon dioxide hydrogenation catalysts based on natural aluminosilicate nanotubes and zeolite H-ZSM-5 are synthesized. Their textural and acidic properties are studied via low-temperature nitrogen adsorption–desorption, temperature-programmed desorption of ammonia, temperature-programmed reduction of hydrogen, and elemental analysis. The effect the temperatures of the reaction have on the conversion of CO2 and distribution of its product is studied. Catalysts based on aluminosilicate halloysite nanotubes exhibit methanol and С2–С4 hydrocarbon selectivities of 88 and 16%, respectively.

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Funding

This work was performed as part of program no. АААА-А21-121011590083-9 “Fundamentals of the Development of Metallic and Composite Materials” of the Center for Information Technologies and Systems of Executive Authorities.

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Authors and Affiliations

  1. Gubkin State University of Oil and Gas, 119991, Moscow, Russia

    E. M. Smirnova, M. V. Reshetina, N. R. Demikhova, V. A. Vinokurov & A. P. Glotov

  2. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    N. D. Evdokimenko, A. L. Kustov, S. F. Dunaev & A. P. Glotov

Authors
  1. E. M. Smirnova
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  2. N. D. Evdokimenko
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  3. M. V. Reshetina
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  4. N. R. Demikhova
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  5. A. L. Kustov
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  6. S. F. Dunaev
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  7. V. A. Vinokurov
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  8. A. P. Glotov
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Corresponding author

Correspondence to E. M. Smirnova.

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Translated by M. Timoshinina

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Smirnova, E.M., Evdokimenko, N.D., Reshetina, M.V. et al. Fe- and Cu–Zn-Containing Catalysts Based on Natural Aluminosilicate Nanotubes and Zeolite H-ZSM-5 in the Hydrogenation of Carbon Dioxide. Russ. J. Phys. Chem. 97, 1395–1401 (2023). https://doi.org/10.1134/S0036024423070270

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  • DOI: https://doi.org/10.1134/S0036024423070270

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