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Cyclization of isoprene compounds

Report 20. Cyclization of the esters of geranic acid under the influence of cationic initiators

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Reaction of geranic ester with cationic initiators of the type RCOMXn+1, depending on the nature of the R radical and the anion MX −n+1 , leads to the formation of cyclic or acyclic products containing the radical RCO, or of their mixtures. The factors which determine the trend of the reaction are examined.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    M. Z. Krimer, V. A. Smit, A. V. Semenovskii, V. S. Bogdanov & V. F. Kucherov

Authors
  1. M. Z. Krimer
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  2. V. A. Smit
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  3. A. V. Semenovskii
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  4. V. S. Bogdanov
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  5. V. F. Kucherov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 866–874, April, 1968.

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Krimer, M.Z., Smit, V.A., Semenovskii, A.V. et al. Cyclization of isoprene compounds. Russ Chem Bull 17, 828–834 (1968). https://doi.org/10.1007/BF00905763

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  • DOI: https://doi.org/10.1007/BF00905763

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