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Organoboron compounds

Communication 100. Reactions of esters of thioboric and thio organoboron acids with carbonyl compounds

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Thioboric esters react with ketones and aldehydes with formation of boric anhydride and the corresponding thioketals or thioacetals.

  2. 2.

    Dibutyl dithiobenzeneboronate reacts with acetone with formation of phenylboron oxide and acetone dibutyl thioketal.

  3. 3.

    Under the action of acetone butyl diarylthioborinates are converted into the bis(diarylboron) oxide and arylboron oxide with formation of acetone dibutyl thioketal.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    B. M. Mikhailov & N. S. Fedotov

Authors
  1. B. M. Mikhailov
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  2. N. S. Fedotov
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Mikhailov, B.M., Fedotov, N.S. Organoboron compounds. Russ Chem Bull 11, 934–936 (1962). https://doi.org/10.1007/BF00905208

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  • DOI: https://doi.org/10.1007/BF00905208

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