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Über die Darstellung von Trilithium-trisulfimid (Trilithium-1,3,5,2,4,6-trithiatriazin-1,1,3,3,5,5-hexaoxid) und die thermische Zersetzung einiger Salze des Trisulfimids

The formation of trilithiumtrisulfimid (trilithiumhexaoxocyclotrithiazane) and the thermolysis of some trisulfimid salts.

  • Anorganische, Struktur- und Physikalische Chemie
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Abstract

Trilithiumhexaoxocyclotrithiazane* (trilithiumtrisulfimid) has been prepared for the first time by reaction of triammoniumtrisulfimid with LiOH in a solid state reaction and by using high boiling alcohols as reaction medium. The thermolysis of different salts of trisulfimid (Na-, K-, Li-, Ag-, NH4-salt) has been studied by thermoanalytical methods in the region between 25–500 δC. The course of decomposition of these compounds is discussed by IR and chromatographic measurements.

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Authors and Affiliations

  1. Institut für Anorganische und Analytische Chemie der Universität Graz, Österreich

    E. Nachbaur & E. Baumgartner

Authors
  1. E. Nachbaur
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  2. E. Baumgartner
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Mit 2 Abbildungen

Diesen Namen verwendetI. Haiduc in: The Chemistry of Inorganic Ring Systems. Wiley-Interscience. 1970.

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Nachbaur, E., Baumgartner, E. Über die Darstellung von Trilithium-trisulfimid (Trilithium-1,3,5,2,4,6-trithiatriazin-1,1,3,3,5,5-hexaoxid) und die thermische Zersetzung einiger Salze des Trisulfimids. Monatshefte für Chemie 104, 1131–1138 (1973). https://doi.org/10.1007/BF00903932

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  • DOI: https://doi.org/10.1007/BF00903932

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