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A self-consistent method of constructing an effective rotational Hamiltonian

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Abstract

Methods have become widely used in molecular spectroscopy that involve the construction of effective rotational Hamiltonians [1, 2]. One of these methods has been developed by one of us over several years [3, 4]. A simple basis is provided for this method and it is shown that the scheme for constructing the effective operator for the rotational energy is substantially self-consistent.

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Literature cited

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Authors and Affiliations

  1. Institute of Atmospheric Optics, Siberian Division, Academy of Sciences of the USSR., USSR

    Yu. S. Makushkin & V. N. Cherepanov

Authors
  1. Yu. S. Makushkin
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  2. V. N. Cherepanov
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 68–72, May, 1981.

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Makushkin, Y.S., Cherepanov, V.N. A self-consistent method of constructing an effective rotational Hamiltonian. Soviet Physics Journal 24, 449–452 (1981). https://doi.org/10.1007/BF00898409

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  • DOI: https://doi.org/10.1007/BF00898409

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