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Application of a quasichemical variant of the method of cluster components to binary melts

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Abstract

Application of the quasichemical method of cluster components to binary melts in systems with chemical compounds in the solid state and in systems with a simple eutectic is examined. The approach proposed is an extension of the model of quasi-ideal Fischer solutions to an arbitrary number of chemical compounds. In addition to the thermodynamic properties, it permits discussion of different concentration-responsive physical properties of the melts. A computation performed for the systems Pd-Al and Pd-Si exhibited satisfactory agreement with the experimental results.

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Authors and Affiliations

  1. Sverdlovsk Institute of the National Economy, USSR

    V. B. Fetisov & A. N. Men'

  2. Institute of Metallurgy, Academy of Sciences of the USSR, USSR

    V. B. Fetisov & A. N. Men'

Authors
  1. V. B. Fetisov
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  2. A. N. Men'
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 57–60, July, 1977.

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Fetisov, V.B., Men', A.N. Application of a quasichemical variant of the method of cluster components to binary melts. Soviet Physics Journal 20, 881–884 (1977). https://doi.org/10.1007/BF00893132

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  • DOI: https://doi.org/10.1007/BF00893132

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