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Spectral manifestation of structure and symmetry in saturated five-membered heterocycles

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Abstract

This paper considers the spectral transition in different vibrational-spectral regions of cyclopentane to monosubstituted heterocyclic molecules and saturated molecules with two ring heteroatoms. Particular attention is paid to nonplanar-vibrational frequencies and frequencies below 200 cm−1. The latter are interpreted as rotational-rocking frequencies. The essential dependence of low frequencies on the geometric, electrical, and magnetic structure of heterocyclic molecules is demonstrated.

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Authors and Affiliations

  1. Poltava Civil-Engineering Institute, USSR

    R. S. Lebedev

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  1. R. S. Lebedev
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Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 7–13, April, 1972.

The author thanks L. A. Lebedeva for her constant assistance in this work.

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Lebedev, R.S. Spectral manifestation of structure and symmetry in saturated five-membered heterocycles. Soviet Physics Journal 15, 473–478 (1972). https://doi.org/10.1007/BF00892563

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  • DOI: https://doi.org/10.1007/BF00892563

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