Summary
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1.
A study was made of the hydrogenation of mono- and bis-2-cyanoethyl ethers of 2,5-dimethyl-3-hexyne-2,5-diol and 3-hexyne-2,5-diol in presence of palladium and rhodium boride catalysts and palladium black deposited on active birch charcoal.
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2.
Over a palladium boride catalyst the reduction process does not affect the CN group. Over palladium black both the cyano groups and the triple carbon-carbon bond are hydrogenated at a high rate.
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3.
Over a rhodium boride catalyst the reduction process affects both the triple carbon-carbon bond and the cyano groups.
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Yu. S. Zal'kind and I. G. Bezsonova, Zh. russk. fiz.-khim. obshch,53, 279 (1921).
Yu. S. Zal'kind and Z. Neishtab, Zh. russk. fiz.-khim. obshch.,50, 34 (1918).
Yu. S. Zal'kind and P. S. Bataev, Zh. obshch. khimii,17, 1858 (1947).
I. N. Nazarov and G. A. Shvekhgeimer, Zh. obshch. khimii,24, 157 (1954).
N. D. Zelinskii, Zh. russk. fiz.-khim. obshch.,54, 57 (1922).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2176–2179, December, 1966.
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Bataev, P.S., Konstantinova, L.A., Balandin, A.A. et al. Catalytic hydrogenation of acetylenic γ-glycols and their derivatives Communication 1. Hydrogenation of 2-cyanoethyl ethers. Russ Chem Bull 15, 2105–2108 (1966). https://doi.org/10.1007/BF00867709
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DOI: https://doi.org/10.1007/BF00867709