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Synthesis and structure of 1-substituted 1-Oxo-1,2-dihydro-4H-3,1-benzoxaphosphorins

  • Organic Chemistry
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Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

1-X-1-Oxo-1,2-dihydro-4H-3,1-benzoxaphosphorins (X = CH2Cl, Ph, and OH) were obtained by reacting ortho-(butoxymethoxymethyl)phenylmagnesium bromide with derivatives of chloromethylphosphonic and chloromethylphosphinic acids, followed by intramolecular alkylation. X-Ray diffraction was used to study the molecular and crystalline structure of one of these compounds (with X = OH).

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Authors
  1. A. N. Bovin
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  2. A. N. Chekhlov
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  3. E. N. Tsvetkov
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Additional information

Institute of Physiologically Active Substances, Russian Academy of Sciences, 142432 Chernogolovka. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 9, pp. 2174–2180, September, 1992.

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Bovin, A.N., Chekhlov, A.N. & Tsvetkov, E.N. Synthesis and structure of 1-substituted 1-Oxo-1,2-dihydro-4H-3,1-benzoxaphosphorins. Russ Chem Bull 41, 1704–1708 (1992). https://doi.org/10.1007/BF00863597

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  • DOI: https://doi.org/10.1007/BF00863597

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