Skip to main content
SpringerLink
Log in

Dissolution of metallic gold in DMSO-RX systems. The concept of a donor-acceptor electron transfer system

  • Inorganic Chemistry
  • Published:
Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

The complexing of gold during dissolution of gold powder in donor—acceptor organic and aqueous—organic Au0-DMSO-RX systems (where R=H or Bu, and X=Cl or Br) was studied. Ten complexes were produced, and their compositions and IR spectra in the 4000−200 cm−1 range were determined. The data obtained were interpreted in terms of the concept of donor—acceptor electron transfer systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. USSR Inventor's Certificate No. 540,822;Byull. Izobret., No. 48, 62 (1976).

    Google Scholar 

  2. I. P. Lavrentiev, L. G. Korableva, E. A. Lavrentieva, et al.,Trans. Met. Chem. 5, No. 2, 193 (1980).

    Google Scholar 

  3. Ya. A. Letuchii, I. P. Lavrentiev, and M. L. Khidekel,Oxid. Commun. 6, Nos. 1–4, 285 (1984).

    Google Scholar 

  4. N. R. C. Jackson, W. D. Harrison, and D. C. Goodall,J. Chem. Soc., Chem. Commun., No. 11, 729 (1988).

  5. G. A. Nifontova, O. N. Krasochka, I. P. Lavrent'ev, et al.,Izv. Akad. Nauk, Ser. Khim., No. 2, 450 (1988).

  6. G. A. Nifontova, in: 28th Int. Conf. Coord. Chem. Gera, DDR, Vol. 2 (1990), p. 107.

    Google Scholar 

  7. I. P. Lavrent'ev, in: Abstracts of Proceedings of the 14th All-Union Conf. on Chemistry, Analysis, and Technology of Platinum Metals, Novosibirsk (1989), p. 26.

  8. P. L. Goggin, R. J. Goodfellow, S. R. Haddock, et al.,J. Chem. Soc., Dalton Trans., No. 16, 1904 (1972).

  9. J. R. Alkins and P. J. Hendra,Spectrochim. Acta 22, No. 12, 2075 (1966).

    Google Scholar 

  10. E. A. Allen and W. Wilkinson,Spectrochim. Acta 28A, No. 12, 2257 (1972).

    Google Scholar 

  11. P. Biscarini, L. Fusina, G. Nivellini, and G. Pellizzi,J. Chem. Soc., Dalton Trans., No. 6, 664 (1977).

    Google Scholar 

  12. J. A. Greighton, J. H. S. Green, D. J. Harrison, and S. M. Waller,Spectrochim. Acta 23A, No. 12, 2973 (1967).

    Google Scholar 

  13. C. E. Coates and C. Parkin,J. Chem. Soc., No. 2, 421 (1963).

  14. G. A. Nifontova, I. P. Lavrent'ev, A. F. Makarov, and M. L. Khidekel', in: Abstracts of Proceedings of the 11th All-Union Conf. on Chemistry, Analysis, and Technology of Platinum Group Metals, Leningrad (1979), p. 60.

  15. Yu. M. Shul'ga, G. A. Nifontova, I. P. Lavrent'ev, and M. L. Khidekel',Zh. Fiz. Khim. 55, No. 8, 2075 (1981).

    Google Scholar 

  16. E. T. Épel'baum, V. I. Ponomarev, and I. P. Lavrent'ev,Izv. Akad. Nauk, Ser. Khim., No. 4, 934 (1991).

    Google Scholar 

Download references

Authors
  1. G. A. Nifontova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. P. Lavrent'ev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Institute of Structural Macrokinetics, Russian Academy of Sciences, Chernogolovka 142432, Moscow District. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 498–506, March, 1992.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nifontova, G.A., Lavrent'ev, I.P. Dissolution of metallic gold in DMSO-RX systems. The concept of a donor-acceptor electron transfer system. Russ Chem Bull 41, 391–397 (1992). https://doi.org/10.1007/BF00863050

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00863050

Keywords

Search

Navigation