Abstract
Research on the modification of the properties of crystalline polymers by changing their physical structure is reviewed. Two different modification principles are considered — the creation of a homogeneous physical structure (introduction of small amount of highly dispersed regulators of the structure-forming processes) and the creation of an inhomogeneous physical structure (by contact with large regulating surfaces) in order to differentiate the surface from the bulk properties and improve resistance to the development of defects. The question of regulation of the processes of physical structure formation by the introduction of chemically reacting substances is also investigated. The possibilities of using antioxidants as physical modifiers and the possibility of physical modification during both the processing and synthesis of polymers are stressed.
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Literature cited
V. A. Kargin, T. I. Sogolova, and G. Sh. Talipov, Vysokomol. Soed.,5, 1809 (1963).
L. I. Nadareishvili and T. I. Sogolova, Proc. 13th Conf. on High-Molecular-Weight Compounds Program [in Russian], Moscow (1962), p. 8.
T. I. Sogolova, Doctoral Dissertation [in Russian], Moscow (1963).
V. A. Kargin, T. I. Sogolova, and L. I. Nadareishvili, Vysokomol. Soed.,6, 165; 169 (1964).
V. A. Kargin, T. I. Sogolova, and L. I. Nadareishvili, Vysokomol. Soed.,6, 1272 (1964).
V. A. Kargin, T. I. Sogolova, and L. I. Nadareishvili, Vysokomol. Soed.,6, 1407 (1964).
N. P. Pavlichenko and T. I. Sogolova, Proc. 13th Conf. on High-Molecular-Weight Compounds Program [in Russian], Moscow (1962), p. 5.
T. I. Sogolova, Mekhan. Polim., No. 1, 5 (1965).
T. I. Sogolova, Mekhan. Polim., No. 5, 643 (1966).
T. I. Sogolova, in: Progress in Polymer Chemistry and Physics [in Russian], Moscow (1970), p. 232.
V. A. Kargin, T. I. Sogolova, and T. K. Shaposhnikova, Dokl. Akad. Nauk SSSR,156, 1156 (1964).
V. A. Kargin, T. I. Sogolova, and N. Ya. Rapoport-Molodtsova, Dokl. Akad. Nauk SSSR,156, 1406 (1964).
V. A. Kargin, T. I. Sogolova, and N. Ya. Rapoport-Molodtsova, Vysokomol. Soed.,6, 2090 (1964).
V. A. Kargin, T. I. Sogolova, and T. K. Shaposhnikova, Vysokomol. Soed.,7, 229 (1965).
V. A. Kargin, T. I. Sogolova, and N. Ya. Rapoport, Dokl. Akad. Nauk SSSR,163, 1194 (1965).
V. A. Kargin, T. I. Sogolova, and I. I. Kurbanova, Dokl. Akad. Nauk SSSR,162, 1092 (1965).
V. A. Kargin, T. I. Sogolova, and T. K. Shaposhnikova, Vysokomol. Soed.,7, 385 (1965).
V. A. Kargin, T. I. Sogolova, and I. I. Kurbanova, Vysokomol. Soed.,8, 2104 (1966).
V. A. Kargin, T. I. Sogolova, N. Ya. Rapoport, and I. I. Kurbanova, J. Polym. Sci.,C16, 1609.
V. A. Kargin, T. I. Sogolova, and V. M. Rubshtein, Vysokomol. Soed.,A10, 2017 (1968).
V. A. Kargin, T. I. Sogolova, and T. K. Shaposhnikova, Dokl. Akad. Nauk SSSR,180, 901 (1968).
A. G. Savin, T. K. Shaposhnikova, V. L. Karpov, T. I. Sogolova, and V. A. Kargin, Vysokomol. Soed.,A10, 1584 (1968).
V. A. Kargin, T. I. Sogolova, T. K. Shaposhnikova, and N. I. Korshunova, Dokl. Akad. Nauk SSSR,188, 1343 (1969).
V. A. Kargin, T. I. Sogolova, T. K. Shaposhnikova, and N. I. Korshunova, Vysokomol. Soed.,A12, 649 (1970).
N. I. Korshunova, Candidate's Dissertation [in Russian], Moscow (1970).
V. A. Kargin, T. I. Sogolova, N. Ya. Rapoport, V. A. Vorotnikova, and N. A. Slovokhotova, Vysokomol. Soed.,13, 1779 (1971).
L. J. Bellamy, Infra-Red Spectra of Complex Molecules, Methuen (1958).
V. A. Kargin, T. I. Sogolova, and I. I. Kurbanova, Vysokomol. Soed.,7, 2108 (1965).
V. A. Kargin, T. I. Sogolova, and I. I. Kurbanova, Vysokomol. Soed.,8, 1311 (1966).
A. V. Ermolina, I. M. Abramova, M. I. Levantovskaya, and B. M. Kovarskaya, Vysokomol. Soed.,B10, 770 (1968).
G. M. Ozerov and M. S. Akutin, Plast. Massy, No. 10, 29 (1966).
G. I. Kudryavtsev, N. D. Katarzhanov, Yu. A. Voitelev, and V. V. Golubeva, Khim. Volokna, No. 5, 16 (1960).
M. I. Levantovskaya, M. P. Yazvikova, and M. K. Dobrokhotova, Plast. Massy, No. 3, 19 (1963).
M. I. Levantovskaya, B. M. Kovarskaya, G. V. Dralyuk, and M. B. Neiman, Vysokomol. Soed.,6, 1885 (1964).
Additional information
L. Ya. Karpov Scientific-Research Physicochemical Institute, Moscow. Translated from Mekhanika Polimerov, No. 3, pp. 395–408, May–June, 1972.
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Sogolova, T.I. Physical and physicochemical modification of polymers. Polymer Mechanics 8, 353–364 (1972). https://doi.org/10.1007/BF00856358
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DOI: https://doi.org/10.1007/BF00856358